From: Heavy metal removal applications using adsorptive membranes
AMs | Adsorbents | Heavy metal ions | Removal efficiency (%) | Maximum adsorption capacity (mg g−1) | pH | Recycling method | Desorption efficiency (%) | Recycle number | Refs. |
---|---|---|---|---|---|---|---|---|---|
PMs | CTS/PEG nCTS ECH-cCTS GLA-cCTS nCTS ECH-cCTS GLA-cCTS CTS PVT-co-PAN PVA/PEI CTS/PVA/PEI CA/PEI | Fe2+, Mn2+ Hg2+ Hg2+ Hg2+ Cr6+ Cr6+ Cr6+ Cu2+ Cu2+ Pb2+, Cd2+, Cu2+ Cd2+, Cu2+, Ni2+ Cu2+ | – 15.1 18.3 35.2 37.9 45.5, 92.0 86.9, 31.7 97.2 87.4 60.0, 26.0, 16.0 74.8, 57.4, 50.3 14.8 | 38.0, 18.0 25.3 30.3 75.5 885.0 270.0, 1420.0 950.0, 347.0 87.5 44.3 122.2, 37.1, 29.9 112.1, 86.1, 75.5 7.4 | 5.0, 5.9 6.0 6.0 6.0 6.0 2.0, 6.0 2.0, 6.0 5.0 5.0 5.0 6.0 5.0 | 0.1 M HCl 1 M NaCl, 10–4 M EDTA 1 M NaCl, 10–4 M EDTA 1 M NaCl, 10–4 M EDTA 1 M NaCl 1 M NaCl 1 M NaCl 0.03 M H2SO4 0.25 mM HCl, 0.25 mM EDTA 0.05 M HCl, 0.05 M HNO3 0.05 M Na2EDTA 0.1 M HCl |  > 98.0 73.1, 52.3 86.6, 50.5 43.2, 19.9 48.6 77.2, 49.1 40.3, 35.7  ~ 35.0  ~ 78.0, ~ 96.0 98.8, 61.8 (Cu2+)  ~ 80.0 10.5 | 4 – – – 3 3 3 5 – 5 4 3 | [48] [50] [50] [50] [52] [52] [52] [130] [129] [53] [54] [55] |
PCMs | PANOB CMC Al oxide-CMC Fe oxide-CMC Fe oxide-PE8M Fe oxide-PE25M CPBC PANlB CCPM | Cu2+, Zn2+, Cd2+ Se4+ Se4+ Se4+ Cr6+ Cr6+ Cu2+, Zn2+, Cd2+, Ni2+ U6+ Cu2+, Pb2+ | 99.8, 98.9, 97.4 19.0 19.0 15.0 95.0 84.0 95.0, 95.0, 85.0, 70.0 70.5 96.0, 99.5 | 77.4, 65.4, 52.6 18.4 17.2 8.2 8.8 7.7 88.5, 72.9, 51.5, 48.5 14.1 9.6, 19.9 | 2.0–7.0 4.0–4.5 4.0–4.5 4.0–4.5 1.0–9.0 1.0–9.0 6.0, 7.0, 6.0, 8.0 5.0 6.5, 6.0 | 0.1 M HCl NaCl NaCl, NaOH – HCl, NaOH – 0.05 M Ca(NO3)2, 0.05 M EDTA, 0.05 M DTPA 0.1 M HCl 0.1 M HNO3; 0.01 M EDTA |  > 90.0 11.0 15.0, 44.0 – 90.0 –  > 90.0  ~ 68.0 72.1, 66.7; 75.3, 68.0 | 4 – – – – – – 7 – | [58] [59] [59] [59] [60] [60] [65] [66] [67] |
ENMs | AOPAN/RC PEI/PVA PEI/PES TC PAN/PVA PVA CTS PVA/CTS CNC/CTS/PVA-SH PAN/CTS PEI/CTS | Fe3+, Cu2+, Cd2+ Cu2+, Cd2+, Pb2+ Pb2+, Cu2+, Cd2+ Cu2+, Cd2+, Pb2+ Cr6+, Cd2+ Cu2+, Pb2+ Ni2+, Cu2+ Ni2+, Co2+ Cu2+, Pb2+ Cd2+, Pb2+ Cr6+, Cu2+, Co2+ | 31.2, 11.5, 2.9 23.0, 25.6, 32.8 90.4, 89.8, 93.2 4.9, 4.6, 2.2 33.3, 28.0 – 46.0, 68.7 79.3, 77.1 39.4, 44.8 51.1, 52.9 50.33, 27.3, 19.3 | 417.2, 270.7, 127.0 70.9, 121.9, 94.3 94.3, 161.3, 357.1 49.0, 45.9, 22.0 66.5, 33.6 58.3, 161.7 10.3, 25.6 23.9, 10.0 484.1, 323.5 385.0, 240.0 139.0, 69.3, 68.3 | 2.0, 5.0, 6.0 5.0 5.0–7.0 2.0–7.0 2.0, 6.0 – 5.0 6.0 6.0 7.0, 5.0 2.0, 4.0, 6.0 | 0.1 M HCl 0.05 M EDTA, 0.05 M HCl, 0.05 M HNO3 0.05 M EDTA – 0.1 M NaOH, 1 M HNO3 – EDTA – 4 M HCl – 0.01 M HCl, 0.01 M NaOH |  > 70.0 95.6, 51.4, 20.7 (Cu2+) 96.2, 98.2, 97.2 –  > 90.0 – 32.2, 41.8 – 90.6, 90.2 – 40.3, 21.0, 13.3 | 5 3 3 – 3 – 3 – 4 – 5 | [84] [86] [89] [98] [85] [81] [96] [94] [97] [100] [99] |
NEMs | CCGO GO/PSf GO/PVA GO/cellulose AgNPs-St-PEG-AcANCH PAN/MO/CTS PAN/MO pHEMA/CTS CTS/HAp CTS/PVA/Zeo MOFs Zr-MOFs | Cr6+ Cu2+, Cd2+, Pb2+, Cr6+ Cu2+, Ni2+, Cd2+ Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Pb2+ Hg2+ Cd2+, Pb2+ Cd2+, Pb2+ Cd2+, Pb2+, Hg2+ Pb2+, Co2+, Ni2+ Cr6+, Fe3+, Ni2+ Cu2+ Cu2+ | 81.2  > 90.0 72.6, 62.3, 83.8  > 90.0 (from Co2+ to Cd2+), 100.0 (Pb2+)  ~ 90.0, 85.0 61.2, 86.0 36.4, 77.2 37.6, 25.1, 78.4 78.5, 80.0, 55.5  ~ 100.0, 93.0, 98.0 6.0 98.8 | 67.7 75.0, 68.0, 79.0, 154.0 72.6, 62.3, 83.8 15.5, 14.3, 26.6, 16.7, 26.8, 107.9 158.2, 182.5 461.0, 390.0 91.0, 193.0 18.5, 22.7, 68.8 296.7, 213.8, 180.2 8.8, 6.2, 1.8 59.8 988.2 | 3.0 6.5, 6.4, 6.7, 3.5 5.7 4.5 7.0, 6.0 7.0, 5.0 7.0, 5.0 5.0 – – 6.0 6.0 | 0.1 M NaOH DI H2O/HCl 1 M HCl 0.1 M HNO3 – – 0.01 M HNO3 1 M HNO3 DI H2O – – | 76.9  ~ 90.0 64.7, 54.8, 75.2  ~ 98.0 (Pb2+) – –  > 95.0 75.4, 72.5, 52.4 99.0, 92.0, 96.0 – – | 5 3 6 10 – – – 5 5 5 – – | [118] [120] [26] [121] [128] [100] [100] [122] [123] [104] [124] [124] |