Recent progress of eco-friendly manufacturing process of efficient perovskite solar cells

Nano Convergence

Table 1 The safety issues and basic properties of various antisolvents

Solvents	Severely harmful statements in GHS^a	IDLH^b [ppm]	LD₅₀^c [mg/kg]
Limonene	N	–	5200
2-ME	Y	200	1480
2-MeTHF	N	–	300–2000
2-methylpyrazine	N	50	1800
ACN	N	500	2460
Diethyl carbonate	N	–	4900
DMA	Y	300	4300
DMF	Y	500	2800
DMPU	Y	–	1300
DMSO	N	–	14,500
EA	N	2000	5620
EtOH	Y	3300	6000
GBL	N	–	1540
GVL	N	–	8800
IPA	N	2000	5045
Isobutanol	N	1600	3750
MA	N	100	100
MAAc	N	–	-
NMP	N	–	3914
TEP	N	–	500

All the abbreviation for solvents is given in manuscript or following tables
^aGHS: Globally Harmonized System of Classification and Labelling of Chemicals. Severely harmful statements including H340-341 (genetic defects), H350-351 (cancer), H360-361 (damaging fertility or the unborn child), H362 (harm to breast-fed children), and H370-373 (damaging organs)
^bIDLH: Immediately Dangerous to Life or Health Values. All the values are obtained from the website of the National Institute for Occupational Safety and Health (NIOSH), United States
^cLD₅₀: Median Lethal Dose. All the values are obtained from the MSDS documents provided by the supplier, for rat, oral