Open Access

High performance electrochemical and electrothermal artificial muscles from twist-spun carbon nanotube yarn

Nano Convergence20152:8

https://doi.org/10.1186/s40580-014-0036-0

Received: 14 October 2014

Accepted: 28 October 2014

Published: 15 April 2015

Abstract

High performance torsional and tensile artificial muscles are described, which utilize thermally- or electrochemically-induced volume changes of twist-spun, guest-filled, carbon nanotube (CNT) yarns. These yarns were prepared by incorporating twist in carbon nanotube sheets drawn from spinnable CNT forests. Inserting high twist into the CNT yarn results in yarn coiling, which can dramatically amplify tensile stroke and work capabilities compared with that for the non-coiled twisted yarn. When electrochemically driven in a liquid electrolyte, these artificial muscles can generate a torsional rotation per muscle length that is over 1000 times higher than for previously reported torsional muscles. All-solid-state torsional electrochemical yarn muscles have provided a large torsional muscle stroke (53° per mm of yarn length) and a tensile stroke of up to 1.3% when lifting loads that are ~25 times heavier than can be lifted by the same diameter human skeletal muscle. Over a million torsional and tensile actuation cycles have been demonstrated for thermally powered CNT hybrid yarns muscles filled with paraffin wax, wherein a muscle spins a rotor at an average 11,500 revolutions/minute or delivers 3% tensile contraction at 1200 cycles/minute. At lower actuation rates, these thermally powered muscles provide tensile strokes of over 10%.

Keywords

Artificial muscle Yarn muscle Carbon nanotube muscle Electrochemical actuator Thermal actuator

1 Introduction

Carbon nanotube (CNT) sheets drawn from spinnable CNT forests has been investigated for such applications as actuators [1-3], supercapacitors [4,5], solar cells [6], biofuel cells [7], and acoustic speaker [8]. There are many other potential application areas because of such properties as high electrical conductivity, high mechanical properties, optical transparency for single sheets, and high gravimetric surface area [4,9]. Zhang et al. developed methods to produce these sheets from spinnable CNT forest [9] and Lima et al. exploited these sheets for their biscrolling process, in which guest-coated CNT sheets are spun into yarn in which the guest is trapped in helical yarn corridors [10]. These hybrid yarns can contain up to 99 wt% of guest and still remain flexible and retain the original properties of the CNT host and guest materials.

CNT tensile actuators and cantilever-based bending actuators, powered by electricity, fuels, light, or heat, have been developed during the past few decades [11]. While electrostatically driven actuation of forest-drawn CNT sheets can generate giant stokes (220%) and giant elongation rates (3.7 X 104%/s), these ultralight aerogel-based actuators require high voltages and are not scalable in thickness to generate high forces [12]. Electrochemical actuation (by double-layer charge injection) of CNT sheets fabricated by solution processing provides very small strokes (~0.2%) [13]. Torsional and rotational motors that use single nanotubes have been demonstrated [14], but the nanotubes do not produce the actuation.

In this study, we describe methods for producing high performance CNT-based torsional and tensile artificial muscles by processes that involve inserting twist into forest-drawn CNT sheets. All of these muscles use yarn volume expansion (produced either electrochemically or by thermal expansion of a yarn guest) to reversibly generate yarn contraction and yarn untwist [1,2]. Yarn coiling, produced by inserting high twist into the CNT yarn, dramatically amplifies tensile stroke and work capabilities compared with those for non-coiled yarn [2].

2 Review

2.1 Electrochemically driven liquid-state and all-solid-state CNT yarn muscles

The precursor yarns used for electrochemical muscles [1,3] were similarly made as those described for thermally powered hybrid muscles [2]. These yarns were fabricated by drawing CNT sheets from a CNT forest (Figure 1a) and inserting twist into a sheet or sheet stack to make a twisted CNT yarn. Twist insertion during forest draw is shown in Figure 1b. Figure 1c and d show, respectively, SEM images of a twisted, non-coiled single-ply yarn and a coiled single-ply yarn that has been coiled as a result of very high twist insertion. The utilized 300–400 μm high CNT forests, from which the CNT sheets were drawn, were prepared by chemical vapor deposition on an iron-catalyst-supporting silicon wafer, using acetylene gas as the carbon precursor. These forests comprised multi-walled CNTs that had an outer diameter of ~10 nm and contain approximately nine walls.
Figure 1

MWNT sheets and yarn structures for torsional and tensile actuation. SEM images of (a) a CNT sheet being drawn from a CNT forest (which is on the left in this image), (b) Fermat-type twist insertion during spinning a yarn from a CNT forest, (c) a single-ply, twisted, non-coiled CNT yarn, and (d) a single-ply, coiled yarn [2].

By applying a few volts potential between a twist-spun, non-coiled CNT yarn and a counter-electrode in an electrolyte bath (Figure 2a), Foroughi et al. [1] demonstrated that yarn artificial muscles can torsionally rotate a relatively heavy paddle to generate a rotation per length that is over 1000 times higher than for previously reported torsional muscles made from a shape-memory alloy [15], piezoelectric ceramics [16], or conducting polymer [17]. Only one-half of the pictured CNT yarn (which is tethered to prevent torsional end displacement) is submerged in the electrolyte (so that this half provides the torsional actuation, and the second half functions as a return spring to enable highly reversible torsional and tensile actuation). The paddle used to measure torsional rotation was located at near yarn center and the cantilever supporting the top end of the muscle enabled measurement of tensile actuation.
Figure 2

Configuration and results for yarn muscles electrochemically driven in a liquid electrolyte: (a) A two-end-tethered configuration for simultaneously measuring torsional and tensile actuation. (b) Torsional rotation (black) and axial length actuation (blue) versus time for a single-ply, twisted, non-coiled CNT yarn that is half-immersed in 0.2 M TBA.PF6 in acetonitrile and pulsed to +5 V (versus Ag/Ag + reference) and then to 0 V for about 5 s each. (c and d) Paddle rotation and tensile actuation during a cyclic potential scan at 50 mV/s. The electrolytes were 0.1 M BMP.TFSI in propylene carbonate (c) and 0.2 M TBA.PF6 in acetonitrile (d) [1].

Figure 2b shows torsional rotation and tensile actuation versus time for a CNT yarn muscle (with a 40° yarn bias angle for CNT orientation with respect to the yarn axis) that uses the configuration of Figure 2a. The actuating 12 μm diameter yarn functioned as a torsional artificial muscle to provide a reversible 15,000° rotation and a maximum torsional rotation rate of 590 revolutions per minute, while rotating a paddle that was 830 times the diameter of the actuating yarn and 1800 times its mass. To achieve this result the 120 mm long muscle yarn was pulsed to +5 V (versus Ag/Ag + reference) and then to 0 V for about 5 s each (while using as liquid electrolyte 0.2 M tetrabutylammonium hexafluorophosphate (TBA.PF6) in acetonitrile). The initial paddle acceleration from the Figure 2b results was α = 50 rad/s2 (9000°/s2), which together with the paddles moment of inertia, provides a maximum starting torque of 1.85 N · m per kilogram of actuating yarn mass. This specific torque is similar to that achieved by large commercial electric motors (2.5 to 6 N · m/kg). The peak torsional power output (above 61 W/kg, based on actuating yarn mass) can be compared with the 300 W/kg realized by large electric motors. This torsional muscle simultaneously acts as a tensile muscle, thereby providing an additional peak power contribution of 920 W/kg by contracting against the applied 88 MPa load, which is equivalent to lifting a mass 185,000 times the mass of the actuating muscle in 1.2 s.

Figure 2c and d shows that torsional actuation and yarn tensile actuation are correlated and both depend on the size of the electrolyte ion used to compensate electronic charge. When a 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP.TFSI) electrolyte was used (Figure 2c), which has similar van der Waals volumes [18] of the anion (147 Å3) and cation (167 Å3), similar torsional and tensile actuation was shown at both positive and negative potentials. Likewise, the much large actuation during reduction than for oxidation in Figure 2d for the TBA.PF6 electrolyte reflects the larger unsolvated van der Waals volume [18] for the TBA cation (293 Å3) than for the PF6 anion (69 Å3).

While these advances using liquid electrolytes are fundamentally important (and use of the torsional muscles in a microfluidic circuit was demonstrated) [1], more general practical utilization is restricted by the use of a liquid electrolyte bath and the associated need for a containment system, which dramatically degrades the gravimetric and volumetric performance of the overall actuator device.

Lee et al. [3] eliminated these problems by showing that laterally connected anode and cathode CNT yarns could be combined in one torsional yarn muscles (Figure 3), thereby enabling all-solid-state electrochemical muscles that provide giant torsional actuation. Identical twisted, non-coiled anode and cathode yarns were made by inserting twist into forest-drawn CNT sheets, and then infiltrating these yarns with a gel electrolyte (poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP), containing tetraethyl ammonium tetrafluoroborate (TEA.BF4) with propylene carbonate (PC)). These two electrolyte-coated yarns were plied together using opposite twist directions for yarn plying than for the initially introduced yarn twist (Figure 3c, d). This use of opposite twist directions for yarn twist and yarn plying is important, since it results in a torque-balanced system when no voltage is applied between anode and cathode yarns, which enables reversible actuation.
Figure 3

Illustration of yarn fabrication methods for torsional and tensile electrochemical CNT muscles. (a) A CNT sheet was pulled from a CNT forest as twist was inserted to provide yarn for the torsional muscles. Inserting twist into stacks of forest-drawn CNT sheets enabled increases in yarn diameter. (b) A Twisted, non-coiled CNT yarn, containing about 12,000 to 15,000 turns/m of inserted twist when a single CNT sheet was used for yarn fabrication. (c) Anode and cathode yarns infiltrated and coated with PVDF-co-HFP based TEA.BF4 solid gel electrolyte. (d) Illustration of a plied, non-coiled yarn muscle with attached paddle for torsional actuation measurements, which had been over coated with the above electrolyte after plying two identical electrolyte-filled CNT yarns. (e) Illustration of the insertion of additional twist to produce yarn coiling, which was deployed to provide the fully coiled yarns used for tensile muscles. (f) Fully-coiled yarn used as both muscle anode and cathode for tensile muscles. (g) Coiled anode and cathode yarns that are infiltrated and coated with PVA-based H2SO4 solid gel electrolyte. (h) Illustration of a plied, coiled yarn muscle with attached weight for tensile actuation measurements, which had been over coated with the above electrolyte after plying [3].

Torsional actuation was obtained using the configuration of Figure 3d, where a one-end-tethered, plied, non-coiled yarn supports a paddle on the free end. Fast, reversible torsional strokes (14-53°/mm) with small hysteresis resulted when using a PVDF-co-HFP/TEA.BF4/PC solid gel electrolyte and applied square-wave voltages between 2.5 and 5 V (Figure 4a and b). A gravimetric peak torque of 0.067 N•m/kg (3.05 nN•m) was generated for this 29 μm diameter yarn by applying a square-wave voltage of 5 V.
Figure 4

Torsional and tensile actuation for all-solid-state electrochemical CNT muscles. (a) Torsional rotation per muscle length, in response to different applied square-wave voltages, which were measured by paddle rotation for a two-ply, twist-spun, CNT yarn that was impregnated with PVDF-co-HFP/TEA.BF4/PC solid gel electrolyte. The direction of yarn twist was opposite to that applied for yarn plyimg. (b) Data showing the largely non-hysteretic reversal of torsional actuation for the torsional muscle used in (a). (c) Tensile actuation strain and applied voltage versus time for a two-ply yarn muscle, using polyvinyl alcohol/H2SO4 electrolyte, while lifting a 11 MPa load. (d) Tensile actuation for the tensile muscle of (c) during three repeated charge (1 V square wave) and discharge cycles that were followed by a hold period, where the power supply was disconnected. Inset: actuator stroke during an extended hold period where no potential was applied, showing that tensile actuation has a latched state, where actuator stroke is largely maintained for an hour without the need for input power [3].

To obtain enhanced tensile actuation for all-solid-state electrochemical muscles, identical anode and cathode yarns in the muscles were coiled (Figure 3e and f). So that we could more conveniently investigate tensile actuation, large diameter CNT yarns were made by inserting twist into a 30-layer stack of forest-drawn sheets. After simultaneously infiltrating and coating both anode and cathode yarn with an aqueous gel electrolyte (polyvinyl alcohol (PVA) in 1 M aqueous sulfuric acid) left-handed coiled electrodes (Z twist) were plied by S twist (right-handed twist) to form a torque-balanced, two-ply, solid-state muscle (Figures 3g and h).

A reversible 0.52% tensile contraction was obtained for this electrochemical muscle (in the configuration of Figure 3h) when a square-wave voltage of 1V was applied to lift a load that provided an 11 MPa stress (Figure 4c). This load lifting capability is 27 times that of human skeletal muscle. Importantly, this electrochemically driven all-solid-state muscle provided a latched state, where charging-induced contraction was largely maintained after subsequent disconnection from the power supply (Figure 4d). In fact, 91.5% of the muscle contraction was maintained for one hour following discontinuation of the applied voltage.

2.2 Thermally and electrothermally powered CNT yarn hybrid muscles

This last category of twist-spun yarn muscles is powered by temperature changes, which can be produced by such processes as electrical heating (using the electrical conductivity of the CNTs), changes in environmental temperature, absorption of light or other electromagnetic radiation, or chemical reactions. These muscles are called hybrid CNT yarn muscles, since the thermally driven volume expansion of a guest within the twist-spun CNT yarn drives the reversible contraction of tensile muscles and the yarn untwist that provides torsional actuation [2]. The main function of the CNT yarn is to confine this actuating yarn guest, insure mechanical durability, enable electrical heating, and provide a helical geometry that can enable torsional actuation and amplify the effect of volume change on tensile actuator stroke.

The methods for making the twisted and coiled CNT yarns are like those above described for the electrochemical methods, and various methods can be used for incorporating high volume fractions of guest in these yarns. These methods include, for example, melt or solution infiltration (which can be followed by in situ polymerization) and biscrolling, in which the guest is deposited on a CNT sheet before twist insertion [2]. Use of paraffin wax as guest provides large yarn volume changes, and thereby large torsional and tensile strokes, so the experimental results described herein use this guest for hybrid yarn muscles.

As is true, for the twist-spun electrochemical muscles, yarn muscle structure and the type of end tethering is key for enabling large muscle strokes (tensile and torsional), as well as long muscle cycle lifetimes. One hundred tensile actuation cycles during lifting have been demonstrated for electrochemically powered a plied, coiled CNT yarn muscle (Figure 5). The tensile actuation did not significantly change during cycles. The chirality of yarn twist versus that of yarn plying is important for determining muscle performance, as is the relative chirality of possibly different segments in a yarn muscle. As a more precise refinement generalization of previous nomenclature [2], we here define a muscle yarn segment as homochiral or heterochiral according to whether or not this segment has the same or different chiralities for yarn twist and yarn plying in this segment.
Figure 5

Cycling stability of electricochemically driven tensile actuator in solid electrolyte. (a) Tensile actuation versus time for 100 actuation cycles of the muscle of Figure 3h. (b,c) The first and last 20 actuation cycles of (a) using an expanded time scale.

Figure 6 shows the different muscle structures and configurations that have experimentally investigated for these hybrid yarns [2]. Using opposite chirality plied yarn segments (which are each homochiral), with a paddle at their interconnection (Figure 6d), maximizes initial torque on the paddle, because these segments operate additively to generate rotation. For the same two-ply homochiral yarn, but without segmentation into sections having opposite chirality, the one-end–tethered configuration of Figure 6c provides twice the torsional rotation of the Figure 6d configuration, but one-half the initial torque, so both configurations provide equal torsional work capacity. Actuation of one segment in a two-end–tethered yarn (Figure 6b) generates smaller paddle rotation than for the same yarn in the configuration of Figure 6d (where two opposite chirality segments are used and both are actuated) because of the energetic cost of twisting the unactuated yarn as the actuating yarn untwists. As for the Figure 6c configuration, the Figure 6d configuration with non-plied yarn does not provide reversible actuation unless internally constrained by a solid guest, to prevent left-handed twist (Z twist) in one muscle segment from canceling right-handed twist (S twist) in the other yarn segment. Since untwist of the actuating segment is compensated by up-twist of the non-actuated segment in Figure 6a, this actuator configuration can optimize tensile contraction per actuated muscle length. Since the entire yarn untwists during actuation for the Figure 6c and d configurations (and this untwist lengthens the muscle), they do not provide maximized percent tensile contraction.
Figure 6

Muscle configurations for tensile and torsional actuation. Tensile load and paddle positions for (a) a two-end–tethered, fully-infiltrated, coiled, homochiral, single-ply yarn; (b) a two-end–tethered, bottom-half–infiltrated, non-coiled, twisted homochiral single-ply yarn; (c) a one-end–tethered, four-ply, fully-infiltrated homochiral yarn; and (d) a two-end–tethered, two-ply, fully-infiltrated yarn muscle comprising two homochiral segments having opposite chiralities [2]. Arrows indicate the observed direction of paddle rotation during thermal actuation. Red and green yarn-end attachments are tethers, meaning they prohibit end rotation; red attachments also prohibit translational displacement.

Although other guest materials can be used to obtain high performance tensile and torsional hybrid yarn muscles (some of which are more suitable for use in extremely low and high temperature ranges), the presently described results are for prototypical hybrid muscles that use paraffin wax guest. Figure 7a shows the dramatic increase in tensile actuator stroke that results from the incorporation of paraffin wax in a twist-spun, coiled CNT yarn and the figure inset shows the much smaller thermo-dimensional changes that occur for twisted, non-coiled yarns that either contain wax or are free of guest. Figure 7b shows that yarn twist insertion to produce complete coiling results in a large tensile actuator contraction when the neat yarn is heated to extreme temperatures: a 7.3% reversible tensile contraction upon heating to ~2560°C under 3.8-MPa tensile stress, corresponding to 0.16 kJ/kg of contractile work capability per yarn weight. The stroke for highly coiled, wax-filled yarn decreases at low applied stresses (Figure 7c), which is consistent with the close proximity of adjacent coils hindering contraction. This figure shows that there is an optimal amount of coiling that maximizes either stroke or work during contraction for the wax hybrid yarn. A maximum contraction of 5.6% was observed at 5.7 MPa stress for a coiled CNT yarn having intermediate twist. Adding 6.8% more twist to the coiled yarn increased the stress of maximum contraction (16.4 MPa for 5.1% strain) and the maximum measured contractile work (1.36 kJ/kg for 84 MPa load).
Figure 7

Thermal tensile actuation for two-end–tethered homochiral yarns. (a) Tensile actuation strain versus temperature before (black) and after (red) wax infiltration for a coiled yarn having an applied stress of 6.8 MPa. Inset: Corresponding actuation data before (black) and after (red) wax infiltration for a non-coiled yarn having an applied stress of 4.8 MPa. (b) Electrothermal tensile actuation strain and work capacity during contraction in vacuum as a function of applied electrical power for a neat, coiled CNT yarn. Insets: Tensile actuation versus estimated temperature for this neat yarn (left) and photograph of the incandescent yarn lifting a 10 g load. Closed symbols and open symbols in (a) and (b) are for increasing and decreasing temperature, respectively. (c) The stress dependence of steady-state tensile actuation and contractile work (black and blue data points, respectively) produced by Joule heating (0.19 V/cm) for a 150-mm-diameter, coiled yarn having different levels of inserted twist [2].

Fast, highly reversible torsional actuation was demonstrated for 2 million cycles for two-end–tethered, half-wax–infiltrated homochiral yarn that rotated a paddle at yarn midpoint (Figure 6b configuration). The hybrid yarn accelerated a 16.5 times-heavier paddle to a full-cycle–averaged 11,500 rotations per minute—first in one direction and then in reverse (Figure 8a). Figure 8b shows the dependence of torsional rotation on input electrical power and applied tensile load for a similar yarn that rotated a 150-times-heavier paddle for a million highly reversible cycles. The average speed was 7,600 revolutions/minute.
Figure 8

Torsional actuation for two-end–tethered, wax-infiltrated yarns. (a) Average rotation rate versus cycle number when excited by a 15 Hz, 40 V/cm, square-wave voltage using 50% duty cycle and 41 MPa applied load. Each point on the graph is the average speed over 120 cycles. Inset: rotation angle and rotation speed versus time for one complete cycle (b) Average rotation rate versus applied electrical power for different tensile loads when using the yarn of (a) and a heavier paddle. Inset: rotation angle and speed versus time for 51.5 MPa load [2].

3 Conclusions

The reviewed work on twist-spun CNT artificial muscles demonstrates the extremely high torsional and tensile muscle performance than can be obtained by the use of twisted, non-coiled and twisted, coiled CNT yarns. The liquid-electrolyte-based twisted, non-coiled muscles (1) generate highly reversible torsional rotation (250°/mm of muscle length), which is 1000 times that for prior-art muscles, as well as a 590 revolutions/minute maximum rotation rate that was maintained for 30 full rotations and (2) a gravimetric peak torsional power output similar to that of large, high-power electric motor [1]. While the demonstrated use of these muscles for microfluidic circuits might become practical, the need for an electrolyte bath and associated confinement system is problematic (especially since it dramatically increases system weight and volume).

To eliminate this problem, our team has further demonstrated thermally powered CNT hybrid muscles and all-solid-state electrochemical CNT muscles that can be operated in air [2,3]. Paraffin-wax-filled thermally powered CNT hybrid muscles provides 2 million cycles of torsional actuation without evidence of performance decrease with cycling and an average torsional rotation speed of 11,500 rpm (20 times that of our electrochemical torsional muscles). When configured as coiled tensile muscles, these wax-hybrid muscles generated 27.8 kW/kg of power during muscle contraction, which is 80 times that for natural skeletal muscles and 30 times that we realized for our electrochemical, liquid-electrolyte CNT muscles.

We next invented all-solid-state electrochemical muscles that avoid the problems of our liquid electrolyte electrochemical muscles - since no liquid bath and associated confinement system is needed, the actuator volume and weight is only that of coupled anode and cathode muscle fibers and associated relatively minor amount of gel electrolyte [3]. The presently realized torsional muscle stroke for plied electrochemical CNT anode and cathode (53°/mm of muscle length) is giant compared with muscles other than described here, but still smaller than the 250°/mm of muscle length that we obtained for liquid-electrolyte-based muscles. Small, but useable, tensile muscle strokes were obtained (1.3% at 2.5 V and 0.52% at 1 V) when lifting loads that are ~25 times heavier than can be lifted by the same diameter human skeletal muscle. Very importantly, in contrast to the case for thermal muscles, we demonstrated the existence of a natural latched state, where stroke (contraction) can be largely maintained with little decrease for an hour when the power supply is disconnected.

There are many opportunities for further improvements in these described actuator technologies, such as in obtaining high electrical-to-mechanical energy efficiencies and large tensile strokes for the all-solid-state electrochemical muscles. More recently realized advances in both areas will be described in the future.

Declarations

Acknowledgments

This work was supported in Korea by the Creative Research Initiative Center for Bio-Artificial Muscle of the Ministry of Science, ICT & Future Planning (MSIP), the MSIP-US Air Force Cooperation Program (NRF-2013K1A3A1A32035592) and the Industrial Strategic Technology Program (10038599) and in the United States by Air Force Grant AOARD-13-4119, Air Force Office of Scientific Research grant FA9550-12-1-0211, and Robert A. Welch Foundation grant AT-0029.

Authors’ Affiliations

(1)
Center for Bio-Artificial Muscle and Department of Biomedical Engineering, Hanyang University
(2)
The Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas

References

  1. J. Foroughi, G.M. Spinks, G.G. Wallace, J. Oh, M.E. Kozlov, S. Fang, T. Mirfakhrai, J.D.W. Madden, M.K. Shin, S.J. Kim, R.H. Baughman, Torsional carbon nanotube artificial muscles. Science 334, 494–497 (2011). doi:10.1126/science.1211220View ArticleGoogle Scholar
  2. M.D. Lima, N. Li, M.J.D. Andrade, S. Fang, J. Oh, G.M. Spinks, M.E. Kozlov, C.S. Haines, D. Suh, J. Foroughi, S.J. Kim, Y. Chen, T. Ware, M.K. Shin, L.D. Machado, A.F. Fonseca, J.D.W. Madden, W.E. Voit, D.S. Galvão, R.H. Baughman, Electrically, chemically, and photonically powered torsional and tensile actuation of hybrid carbon nanotube yarn muscles. Science 338, 928–932 (2012). 10.1126/science.1226762View ArticleGoogle Scholar
  3. J.A. Lee, Y.T. Kim, G.M. Spinks, D. Suh, X. Lepró, M.D. Lima, R.H. Baughman, S.J. Kim, All solid state carbon nanotube torsional and tensile artificial muscles. Nano Lett 14, 2664–2669 (2014). 10.1021/nl500526rView ArticleGoogle Scholar
  4. J.A. Lee, M.K. Shin, S.H. Kim, S.J. Kim, G.M. Spinks, G.G. Wallace, R. Ovalle-Robles, M.D. Lima, M.E. Kozlov, R.H. Baughman, Hybrid nanomembranes for high power and high energy density supercapacitors and their yarn application. ACS Nano 6, 327–334 (2012). doi:10.1021/nn203640aView ArticleGoogle Scholar
  5. J.A. Lee, M.K. Shin, S.H. Kim, H.U. Cho, G.M. Spinks, G.G. Wallace, M.D. Lima, X. Lepro´, M.E. Kozlov, R.H. Baughman, S.J. Kim, Ultrafast charge and discharge biscrolled yarn supercapacitors for textiles and microdevices. Nat Commun 4, 1970 (2013). doi: 10.1038/ncomms2970Google Scholar
  6. J. Velten, Z. Kuanyshbekova, O. Goktepe, F. Goktepe, A. Zakhidov, Weavable dye sensitized solar cells exploiting carbon nanotube yarns. Appl Phys Lett 102, 203902–203902–3 (2013). doi:10.1063/1.4807891View ArticleGoogle Scholar
  7. C.H. Kwon, S.H. Lee, Y.B. Choi, J.A. Lee, S.H. Kim, H.H. Kim, G.M. Spinks, G.G. Wallace, M.D. Lima, M.E. Kozlov, R.H. Baughman, S.J. Kim, High-power biofuel cell textiles from woven biscrolled carbon nanotube yarns. Nat Commun 5, 3928 (2014). 10.1038/ncomms4928Google Scholar
  8. A.E. Aliev, M.D. Lima, S. Fang, R.H. Baughman, Underwater sound generation using carbon nanotube projectors. Nano Lett 10, 2374–2380 (2010). 10.1021/nl100235nView ArticleGoogle Scholar
  9. M. Zhang, S. Fang, A.A. Zakhidov, S.B. Lee, A.E. Aliev, C.D. Williams, K.R. Atkinson, R.H. Baughman, Strong, transparent, multifunctional, carbon nanotube sheets. Science 309, 1215–1259 (2005). doi:10.1126/science.1115311View ArticleGoogle Scholar
  10. M.D. Lima, S. Fang, X. Lepró, C. Lewis, R. Ovalle-Robles, J. Carretero-González, E. Castillo-Martínez, M.E. Kozlov, J. Oh, N. Rawat, C.S. Haines, M.H. Haque, V. Aare, S. Stoughton, A.A. Zakhidov, R.H. Baughman, Biscrolling nanotube sheets and functional guests into yarns. Science 331, 51–55 (2011). 10.1126/science.1195912View ArticleGoogle Scholar
  11. D. Li, W.F. Paxton, R.H. Baughman, T.J. Huang, J.F. Stoddart, P.S. Weiss, Molecular, supramolecular, and macromolecular motors and artificial muscles. MRS Bull 34, 671 (2009). http://dx.doi.org/10.1557/mrs2009.179 View ArticleGoogle Scholar
  12. A.E. Aliev, J. Oh, M. Kozlov, A.A. Kuznetsov, S. Fang, A.F. Fonseca, Giant-stroke, superelastic carbon nanotube aerogel muscles. Science 323, 1575–1578 (2009). 10.1126/science.1168312View ArticleGoogle Scholar
  13. R.H. Baughman, C. Cui, A.A. Zakhidov, Z. Iqbal, J.N. Barisci, G.M. Spinks, G.G. Wallace, A. Mazzoldi, D.D. Rossi, A.G. Rinzler, O. Jaschinski, S. Roth, M. Kertesz, Carbon nanotube actuators. Science 284, 1340–1344 (1999). 10.1126/science.284.5418.1340View ArticleGoogle Scholar
  14. A.M. Fennimore, T.D. Yuzvinsky, W.-Q. Han, M.S. Fuhrer, J. Cumings, A. Zettl, Rotational actuators based on carbon nanotubes. Nature 424, 408–410 (2003). 10.1038/nature01823View ArticleGoogle Scholar
  15. A.C. Keefe, G.P. Carman, Thermo-mechanical characterization of shape memory alloy torque tube actuators. Smart Mater Struct 9, 665 (2000). 10.1088/0964-1726/9/5/311View ArticleGoogle Scholar
  16. J. Kim, B. Kang, Performance test and improvement of piezoelectric torsional actuator. Smart Mater Struct 10, 750–757 (2001). 10.1088/0964-1726/10/4/320View ArticleGoogle Scholar
  17. Y. Fang, T.J. Pence, X. Tan, Fiber-directed conjugated-polymer torsional actuator: nonlinear elasticity modeling and experimental validation. IEEE/ASME Trans Mechatron 16, 656–664 (2011). 10.1109/TMECH.2010.2049366View ArticleGoogle Scholar
  18. M. Ue, A. Murakami, S. Nakamura, A convenient method to estimate ion size for electrolyte materials design. J Electrochem Soc 149, A1385 (2002). 10.1149/1.1507593View ArticleGoogle Scholar

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© Lee et al.; licensee Springer. 2014

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