Skip to main content

Selective synthesis of pure cobalt disulfide on reduced graphene oxide sheets and its high electrocatalytic activity for hydrogen evolution reaction


We synthesized single-phase CoS2 on a large scale by adding graphene oxide of sufficient quantity via the hydrothermal method using cobalt acetate and thioacetamide as precursors; this produced the hybrid of CoS2 with reduced graphene oxide which exhibited high electrocatalytic activity in the hydrogen evolution reaction.

1 Introduction

Considerable efforts have been made toward synthesizing transition metal dichalcogenide (TMD) nanomaterials due to their excellent electronic, optical, and mechanical properties [1, 2]. Among the more notable TMD compounds, MoS2 and WS2, which have electrical properties that can be changed from metallic to semiconducting by varying their crystal structure and the number of layers, have been extensively studied [1]. In addition, the structure and general properties of pyrite-phase TMDs (FeS2, NiS2, and CoS2) have been investigated [36]. These materials have attracted interest for their potential applications; for example, FeS2 with a band gap of 0.95 eV has been used as an active layer in photovoltaic devices and NiS2 has been used as a Li storage material [69]. In particular, CoS2 has received considerable attention due to its metallic behavior, which makes it applicable as an electrocatalyst for oxygen reduction reactions and hydrogen evolution reactions (HERs) [3, 10, 11].

So far, MoS2 and WS2 nanostructures have been extensively explored as electrocatalysts for HER. The overpotentials of MoS2 and WS2 materials occur between −200 and −150 mV and their Tafel slopes fall in the range of 55–40 and 70–58 mV/dec, respectively [2, 12]. Recently, metallic CoS2 has been recognized for its potential as a viable HER catalyst like MoS2. An overpotential of −180 mV and a Tafel slope of 44.6 mV/dec have been measured for CoS2 films synthesized by gas-phase reactions [3]. CoS2 micro- and nanowires have overpotentials of about −100 and –70 mV, respectively, and Tafel slopes of 58.0 and 51.6 mV/dec, respectively [10]. However, CoS2 film is easily damaged by delamination during H2 evolution. Although CoS2 nanowires exhibited the best performance, they became delaminated within three hours. Accounting for a long-term stability, microwires have proven the most effective, despite their limited HER performance. The microstructured surface also helps to convey the H2 bubbles away from the electrode surface, thus maintaining the integrity of the catalyst for HER [10]. On the other hand, the strong performance of CoS2 in HER may result from the oxidation state of sulfur in CoS2, since it is known that S2 2− exhibits higher HER efficiency than S2−. Chang et al. prepared MoSx with S2 2− on 3D Ni foam deposited with graphene layers for electrocatalytic hydrogen evolution and found that MoSx with S2 2− exhibits higher catalytic activity than MoS2 with S2− [13, 14]. Therefore, the HER activity of pure-phase CoS2 should be investigated since it is expected that CoS2 with S2 2− dimer will exhibit favorable performance in HER. As mentioned above, pure-phase CoS2 nanowires and microwires were obtained by the synthesis of cobalt hydroxide carbonate hydrate (Co(OH)(CO3)0.5·xH2O) nanowires and cobalt hydroxide (-Co(OH)2) microwires through a solution-based reaction followed by thermal sulfurization [10]. Additionally, pure-phase CoS2 film has been synthesized by sulfurization of Co film: The substrate on which Co is deposited by an e-beam evaporator is located in the tube furnace and sulfur powder is vaporized by flowing Ar gas at 550 °C [3]. All of the methods are two-step processes, which are limited in terms of mass production. Therefore, it would be worthwhile to establish a method for the large-scale synthesis of pure CoS2.

The hydrothermal reaction is known as a facile method for the large-scale synthesis of CoS2. However, producing pure-phase CoS2 is quite difficult because of the complex stoichiometric compositions of cobalt sulfides such as CoS2, CoS, Co9S8, and Co1−xS that form when the hydrothermal synthesis of CoS2 is attempted using precursors such as cobalt chloride (as cobalt precursor) and thioacetamide, sodium thiosulfate, etc. (as sulfur precursors) [1520]. Indeed, a mixture of cobalt sulfides has been synthesized using the hydrothermal method. For example, Huang et al. found that the flower-like cobalt sulfides prepared by a solvothermal method included a mixture of CoS and Co9S8 (9 %) [15]. Qian et al. then found that as-synthesized cobalt sulfides consisted of CoS2, Co9S8, and Co3S4 when using cobalt chloride in toluene [16]. Furthermore, most reports employed only X-ray diffraction (XRD) for the characterization of CoS2 [1520]. However, in-depth characterization using TEM and XPS as well as XRD is required for the identification of CoS2, due to the existence of various stoichiometric compositions of cobalt sulfides. In addition, impurities such as oxygen can occur in CoS2 since it is susceptible to oxidation in air [10]. Thus, further research is required to allow for the characterization and large-scale production of pure CoS2 with S2 2− dimer.

Herein, we report on such a large-scale synthesis of pure-phase CoS2 on rGO by a one-pot hydrothermal reaction using cobalt acetate and thioacetamide precursors. We demonstrate that GO concentrations of greater than 2 mg/mL are critical in supporting the synthesis of pure-phase CoS2 and inhibiting the oxidation of the CoS2 surface. Furthermore, we provide detailed structural analyses of the synthesized CoS2 and investigate its electrocatalytic activity in HER, thereby demonstrating a long-term stability.

2 Methods

2.1 Synthesis of GO solution

GO was prepared from graphite powder by the modified Hummers’ method.

2.2 Hydrothermal synthesis of CoS2/rGO hybrid

GO solution was added to the mixture of cobalt acetate tetrahydrate (9 mmol) and thioacetamide (90 mmol) and the total volume of the solution was adjusted to 400 mL for all reactions. The solution was transferred to a 500 mL Teflon-lined stainless steel autoclave, heated up to 240 °C, and kept for 24 h. After cooling naturally, the product was filtered, washed with DI water, and dried in vacuum at 60 °C for 12 h. During the hydrothermal process, GO was converted to rGO and CoS2/rGO was formed.

2.3 Characterization

The samples were characterized with field emission scanning electron microscopy (Hitachi, S4800), high-resolution transmission electron microscopy (HRTEM, JEOL JEM-2100 F with probe-Cs corrector, 200 kV), X-ray diffraction [Rikgaku RU-200 diffractometer equipped with Ni-filtered Cu Kα radiation (40 kV, 100 mA, λ = 0.15418 nm)], and X-ray photoelectron spectroscopy (K-alpha, ThermoFisherwith monochromatic Al Kα radiation as the X-ray source). The rGO concentration of samples was characterized with element analyzer (Thermo Scientific, Flash 2000).

2.4 Electrochemical measurements

Electrocatalytic measurements were carried out using a 3-electrode cell and a 0.5 M sulfuric acid (H2SO4) electrolyte solution. A graphite rod (Sigma Aldrich) and Ag/AgCl electrode (Wonatech) were used as counter electrode and reference respectively. The reference electrode was calibrated with respect to reversible hydrogen electrode (RHE) using platinum wires as working and counter electrodes. Materials were dispersed in deionized water at 4 mg/mL and sonicated for 1 h. The ink was then drop-casted onto glassy carbon electrodes of 3 mm diameters (loading 285 µg/cm2) and capped by Nafion (0.5 %, 3 µL, Sigma Aldrich). Linear sweep voltammetry was performed with a 5 mV/s scan rate using a Zive SP2 potentiostat from Wonatech and the electrodes were cycled at least 40 cycles prior to any measurement. The polarization curves were iR-corrected. Electrochemical impedance spectroscopy (EIS) was performed in the frequency range from 1 MHz to 0.1 Hz.

3 Results and discussion

In a typical hydrothermal reaction with CoS2, cobalt precursor such as cobalt chloride reacts with thioacetamide, sodium thiosulfate, etc. to produce CoS2 [1520]. However, the problem with this method involves the generation of impurities such as Co3S4 and Co9S8 along with CoS2, even though they occur in small proportions [15, 16]. Although there are some reports on the synthesis of CoS2/rGO, synthesis of pure CoS2 on rGO sheets has not been clearly demonstrated. It should be noted that these preliminary studies employed small amounts of GO, less than 1 mg/mL, in final reactant solutions for hydrothermal reactions [11, 15, 1821]. Note that growth condition for other reported cobalt sulfide/rGO material is summarized in Additional file 1: Table S1. In this study, we produced pure CoS2 on rGO sheets using GO concentrations of greater than 2 mg/mL. Specifically, we carried out hydrothermal reactions at different concentrations of GO (0.2, 1, 1.6, 2, 2.3, 2.6, and 4 mg/mL) in the synthesis of pure CoS2 (Table 1). Moreover, cobalt acetate tetrahydrate was used as a precursor for Co because it is known that cobalt acetate yields smaller crystal sizes and higher-BET surfaces than cobalt chloride [22, 23]. Each hydrothermal reaction was carried out at 240 °C for 24 h using cobalt acetate tetrahydrate, thioacetamide (TAA), and GO, followed by a washing of the product with distilled water and drying in vacuum at 60 °C. It is noted that 240 °C was determined to be an optimum temperature from experimental results performed at various temperatures (Additional file 1: Figure S1). For reference, the weight percentage of rGO in some final products is provided in Additional file 1: Table S2. As a control experiment, hydrothermal reaction was also performed without GO, producing a mixture of Co3S4, CoS, and CoS2 (see the XRD data in Fig. 1a below). Interestingly, a hybrid of pure CoS2 and rGO (CoS2/rGO) was obtained when more than 2 mg/mL of GO was added. It is worth noting that GO is partially reduced during reaction, meaning that the product is CoS2/rGO. Actually, Co2+ ions can be linked into the functional groups of GO sheets to form strong Co2+-linked GO cylinders [24].

Table 1 Experimental conditions for CoS2/rGO synthesis with various concentrations of GO
Fig. 1
figure 1

a XRD patterns of CoS2/rGO. Cobalt sulfides without GO (black) and CoS2/rGO with 1 mg/mL GO (red) and 2.3 mg/mL GO (blue) compared with standard patterns for CoS2 (navy lines), CoS (pink lines), Co3S4 (green lines), and Co3O4 (violet lines). b Raman spectrum of CoS2/rGO with 2.3 mg/mL GO

Consequently, it is expected that these cobalt ions are protected from unexpected reaction, meaning that CoS2 on rGO is produced, whereas free cobalt ions undergo unwanted reactions during hydrothermal reaction to yield Co3S4, Co9S8, and other cobalt sulfides. Furthermore, rGO sheets play a role as an oxidation-resistance layer for cobalt sulfides. CoS0 covered by rGO was not oxidized, while Co3S4 obtained without GO became oxidized to Co3O4. It is generally known that cobalt sulfides are easily oxidized in air (See the XPS data in Fig. 2 below) [10]. These results are supported by a previous report on the oxidation resistance of multilayer rGO [25]. Since dimeric S2 2− in VS4 can be obtained on graphitic layers, such as those in rGO and carbon nanotubes [26], the formation of pure CoS2 on rGO sheets is not unexpected.

Fig. 2
figure 2

X-ray photoelectron spectra of the a Co 2p and b S 2p regions for CoS2 without GO (black) and for CoS2/rGO with 1 mg/mL GO (red) and 2.3 mg/mL GO (blue)

Scanning electron microscopy (SEM) images of CoS2/rGO with different concentrations of GO and a mixture of cobalt sulfides without GO are shown in Fig. 3. In the absence of GO, an aggregation of particles occurred (Fig. 3a and the TEM images in Additional file 1: Figure S2). On the other hand, CoS2 nanoparticles were covered by the rGO sheets for GO concentrations of 1 and 2.3 mg/mL (Fig. 3b, c). The transmission electron microscopy (TEM) images also demonstrate the growth of single-crystalline CoS2 nanoparticles on the rGO sheets (Fig. 3d, e). Figure 3e shows the rGO sheets with an interlayer d-spacing of 0.34 nm, which corresponds to the d-spacing of graphite, surrounding the CoS2. Figure 3f shows CoS2 nanoparticles with a d-spacing of 0.25 nm, which corresponds to the inter-planar spacing of the (210) plane of the cubic phase. In addition, the SAED pattern establishes the single-crystalline nature of the CoS2 particles (inset of Fig. 3f). To identify the stoichiometry of Co and S, an elemental mapping of the CoS2/rGO hybrids was performed via energy-dispersive X-ray spectroscopy (EDX); this mapping indicated that the ratio of S to Co was 2 (Additional file 1: Figure S3). Note that the C and O in the EDX spectrum are attributed to the rGO.

Fig. 3
figure 3

SEM images of CoS2 particles a without GO, b with 1 mg/mL GO, and c with 2.3 mg/mL GO. d Low magnification TEM image of CoS2/rGO with 2.3 mg/mL GO. e An enlarged TEM image of CoS2/rGO and f a high resolution TEM image of CoS2, the latter showing d-spacing of 0.27 nm in the (200) plane. The inset in f provides a diffraction pattern of the CoS2 in the white square

Figure 1a shows the X-ray diffraction (XRD) spectra of the products according to GO concentration. When GO is not added, there are not only reflections of CoS2 such as the (200), (220), and (311) planes, but also reflections for CoS, Co3S4, and Co3O4. This result is in good agreement with previous reports stating that multiphase cobalt sulfides are usually synthesized in these conditions [15, 16]. Note that CoS was partially observed along with CoS2 for a 1 mg/mL GO concentration (Fig. 1a, JCPDS 75-0605). This result is consistent with the TEM results, which indicate a d-spacing corresponding to the (100) plane of hexagonal-phase CoS within the CoS2/rGO products (Additional file 1: Figure S4, space group P63/mmc; a = 3.384 Å, c = 5.16 Å). In addition, our XRD pattern for CoS2/rGO did not show signs of oxidation, while the non-GO Co3S4 showed a pattern for Co3O4 (Fig. 1a, JCPDS 42-1448; JCPDS 80-1543). Furthermore, we calculated the average crystal size by Scherrer formula using the (200) plane. The results show 36.65 nm and 33.82 nm for the CoS2/rGO (2.3 mg/mL) and CoS2/rGO (1 mg/mL), respectively. These results are well matched with the SEM data in Fig. 3. Note that XRD spectra for CoS2/rGO samples with various GO concentrations in Table 1 are shown in Additional file 1: Figure S5 and pure-phase CoS2 was obtained when GO concentration is higher than 2 mg/mL. A representative Raman spectrum of CoS2/rGO (2.3 mg/mL of GO) is shown in Fig. 1b. Characteristic peaks for CoS2 at 288, 388, and 484 cm−1 corresponding to the Eg, Ag, and Tg(3) modes, respectively [27], and the D and G bands of rGO, can be clearly seen.

To verify the oxidation states of the elements in the CoS2/rGO products, we measured their X-ray photoelectron spectroscopy (XPS) spectra (Fig. 2). The peaks for the binding energy of Co 2p3/2−1/2 appeared at 778.8 and 794 eV for the CoS2/rGO sample with 1 mg/mL GO and at 779 and 794.2 eV for the sample with 2.3 mg/mL GO, indicating an oxidation state of Co2+ (Fig. 2a) [10]. The peaks around 786 and 803 eV are associated with the shake-up type peaks of the 2p3/2-1/2 and peaks at 782.3 and 798 eV are associated with Co3+ from the mixture of cobalt sulfides without GO [28]. For the case of S 2p3/2-1/2, doublet peaks appear at 162.9 and 164 eV for the CoS2/rGO with 1 mg/mL GO sample and at 162.6 and 163.9 eV for the CoS2/rGO with 2.3 mg/mL GO sample, indicating the presence of S2 2− (Fig. 2b) [10]. Note that there is an additional peak at ~161.8 eV for S2− in the CoS2/rGO with 1 mg/mL GO sample and cobalt sulfides without rGO [29]. Although CoS2 is easily oxidized in air as mentioned above [10], our results show no peak for oxidation in any of the CoS2/rGO samples, while there is a substantial oxidation peak at 169.1 eV for the non-GO sample in Fig. 2b, which is consistent with the XRD spectra. Consequently, the XPS results confirm the pure-phase nature of the CoS2 for GO concentration of 2.3 mg/mL.

To explore practical viability, HER tests with the CoS2/rGO samples on glassy carbon electrodes were carried out using a three-electrode cell with a 0.5 M sulfuric acid electrolyte. Polarization curves (I–V plots) were taken for CoS2/rGO samples (1 and 2.3 mg/mL GO) along with a mixture of cobalt sulfides without GO (Fig. 4a). The overpotential of the 2.3 and 1 mg/mL GO samples were found to be −150 and −180 mV versus RHE, respectively. The overpotentials required to drive current densities of 10 mA/cm2 were 228 mV for the 2.3 mg/mL GO sample and 250 mV for the 1 mg/mL GO sample. The mixture of cobalt sulfides without GO exhibited HER activity with an overpotential of −280 mV versus RHE. The Tafel plots derived from these data are shown in Fig. 4b wherein the linear portions were fitted to the Tafel equation to determine the slopes. The Tafel plots reveal a slope of 71 mV/dec for the mixture of cobalt sulfides without GO, 55 mV/dec for CoS2/rGO with 1 mg/mL GO, and 48 mV/dec for CoS2/rGO with 2.3 mg/mL GO. The lower Tafel slope value for the CoS2/rGO hybrid materials, compared to the non-GO sample, can be attributed to the contribution of CoS2 as an active material and the presence of conductive rGO. The pure-phase catalyst clearly plays a key role in revealing the intrinsic activity of CoS2, and the metallic property of CoS2 allows efficient charge transport from the electrode to the surface of the catalysts, which is desired for high-performance electrocatalysts [10]. It should also be noted that the impedance results indicate a lower resistance in the CoS2/rGO electrode with 2.3 mg/mL GO than with 1 mg/mL GO (Fig. 4c). Thus, the formation of an interconnected conducting rGO network can facilitate rapid electron transfer from the electrode to the catalyst. This tendency that the CoS2/rGO electrode with 2.3 mg/mL GO showed higher catalytic activity than that with 1 mg/mL GO was also confirmed in the capacitive current for each CoS2 electrode as a function of scan rate which reveals the double layer capacitance (Additional file 1: Figure S6). The HER performance for the CoS2/rGO samples with various concentrations of GO was also measured (Additional file 1: Figure S7). Considering the onset potentials and Tafel slopes, we found that 2 and 2.3 mg/mL represent optimized concentrations of GO in terms of HER performance. With concentrations lower than 2.0 mg/mL, CoS is partially included and resistance is relatively high. With 4 mg/mL, rGO is expected to hinder the exposure of CoS2 as a catalyst, and the charge-transfer resistance of the CoS2/rGO sample increased slightly (Additional file 1: Figure S8). Recently, the performance of HER for CoS2 film (overpotential of −180 mV and Tafel slope of 44.6 mV/dec) was reported [3]. Thus, the onset potential and Tafel slope values of CoS2/rGO (2.3 mg/mL GO) are roughly commensurate with those of the CoS2 film. However, our catalysts have an improved a long-term stability than that reported for the CoS2 film, which is relatively limited. That is, CoS2 films are known to become delaminated with a physical loss of catalysts occurring within 1 h during cycling. However, CoS2/rGO electrodes maintain hydrogen evolution at Jcathodic = 10 mA/cm2 with minimal change in the applied overpotential, as shown in Fig. 4d. It is noted that the phase and structure of CoS2/rGO maintained after the cycling for 14 h (Additional file 1: Figure S9). After 15 h, the catalysts became delaminated. We summarize the HER performance for various CoS2 structures in the literature, including our results in Additional file 1: Table S3.

Fig. 4
figure 4

Catalytic activity for hydrogen evolution reactions. a Polarization curves (iR-corrected) of Pt wires (green), the mixture of cobalt sulfide without GO (black), and CoS2/rGO samples with 1 mg/mL GO (blue) and with 2.3 mg/mL GO (red). b Tafel analysis of the data shown in a. c Electrochemical impedance spectroscopy (EIS) for CoS2/rGO samples. d Long-term stability measurements for CoS2/rGO samples

4 Conclusions

In summary, we successfully synthesized CoS2/rGO with pure-phase CoS2 on rGO sheets via hydrothermal reaction. The CoS2/rGO hybrid materials exhibited high catalytic activity for HER: overpotential of −150 mV versus RHE and a Tafel slope of 48 mV/dec for CoS2/rGO (2.3 mg/mL GO). Thus, the present study demonstrates the large-scale synthesis of CoS2/rGO hybrids with a long-term stability and strong HER performance.


  1. Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Nat. Nanotechnol. 7, 699–712 (2012)

    Article  Google Scholar 

  2. M. Chhowalla, H.S. Shin, G. Eda, L.-J. Li, K.P. Loh, H. Zhang, Nat. Chem. 5, 263 (2013)

    Article  Google Scholar 

  3. D. Kong, J.J. Cha, H. Wang, H.R. Lee, Y. Cui, Energy Environ. Sci. 6, 3553–3558 (2013)

    Article  Google Scholar 

  4. D. Kong, H. Wang, Z. Lu, Y. Cui, J. Am. Chem. Soc. 136, 4897–4900 (2014)

    Article  Google Scholar 

  5. D.-W. Wang, Q.-H. Wang, T.-M. Wang, CrystEngComm 12, 755–761 (2012)

    Article  Google Scholar 

  6. J. Puthussery, S. Seefeld, N. Berry, M. Gibbs, M. Law, J. Am. Chem. Soc. 133, 716–719 (2011)

    Article  Google Scholar 

  7. R. Morrish, R. Silverstein, C.A. Wolden, J. Am. Chem. Soc. 134, 17854–17857 (2012)

    Article  Google Scholar 

  8. J.S. Jirkovsky, A. Bjorling, E. Ahlberg, J. Phys. Chem. C 116, 24436–24444 (2012)

    Article  Google Scholar 

  9. Q. Wang, L. Jiao, Y. Han, H. Du, W. Peng, Q. Huan, D. Song, Y. Si, Y. Wang, H. Yuan, J. Phys. Chem. C 115, 8300–8304 (2011)

    Article  Google Scholar 

  10. M.S. Faber, R. Dziedzic, M.A. Lukowski, N.S. Kaiser, Q. Ding, S. Jin, J. Am. Chem. Soc. 136, 10053–10061 (2014)

    Article  Google Scholar 

  11. H. Wang, Y. Liang, Y. Li, H. Dai, Angew. Chem. Int. Ed. 50, 10969–10972 (2011)

    Article  Google Scholar 

  12. J. Yang, H.S. Shin, J. Mater. Chem. A 2, 5979–5985 (2014)

    Article  Google Scholar 

  13. Y.-H. Chang, C.-T. Lin, T.-Y. Chen, C.-L. Hsu, Y.-H. Lee, W. Zhang, K.-H. Wei, L.-J. Li, Adv. Mater. 25, 756–760 (2013)

    Article  Google Scholar 

  14. Y.-H. Chang, F.-Y. Wu, T.-Y. Chen, C.-L. Hsu, C.-H. Chen, F. Wiryo, K.-H. Wei, C.-Y. Chiang, L.-J. Li, Small 10, 895–900 (2013)

    Article  Google Scholar 

  15. G. Huang, T. Chen, Z. Wang, K. Chang, W. Chen, J. Power Sources 235, 122–128 (2013)

    Article  Google Scholar 

  16. X.F. Qian, X.M. Zhang, C. Wang, Y. Xie, Y.T. Qian, Inorg. Chem. 38, 2621–2623 (1999)

    Article  Google Scholar 

  17. C. Zhao, D. Li, Y. Feng, J. Mater. Chem. A 1, 5741–5746 (2013)

    Article  Google Scholar 

  18. Z.-D. Meng, K. Ullah, L. Zhu, S. Ye, W.-C. Oh, Mater. Sci. Semicond. Process. 27, 173–180 (2014)

    Article  Google Scholar 

  19. J. Xie, S. Liu, G. Cao, T. Zhu, X. Zhao, Nano Energy 2, 49–56 (2013)

    Article  Google Scholar 

  20. B. Qiu, X. Zhao, D. Xia, J. Alloys Compd. 579, 372–376 (2013)

    Article  Google Scholar 

  21. S. Peng, L. Li, X. Han, W. Sun, M. Srinivasan, S.G. Mhaisalkar, F. Cheng, Q. Yan, J. Chen, S. Ramakrishna, Angew. Chem. Int. Ed. 53, 12594–12599 (2014)

    Google Scholar 

  22. J. Panpranot, S. Kaewkun, P. Praserthdam, J. Goodwin Jr, Catal. Lett. 91, 95–102 (2003)

    Article  Google Scholar 

  23. F. Haga, T. Nakajima, K. Yamashita, S. Mishima, React. Kinet. Catal. Lett. 63, 253–259 (1998)

    Article  Google Scholar 

  24. X. Jiang, Y. Ma, J. Li, Q. Fan, W. Huang, J. Phys. Chem. C 114, 22462–22465 (2010)

    Article  Google Scholar 

  25. D. Kang, J.Y. Kwon, H. Cho, J.-H. Sim, H.S. Hwang, C.S. Kim, Y.J. Kim, R.S. Ruoff, H.S. Shin, ACS Nano 6, 7763–7769 (2012)

    Article  Google Scholar 

  26. C.S. Rout, B.-H. Kim, X. Xu, J. Yang, H.Y. Jeong, D. Odkhuu, N. Park, J. Cho, H.S. Shin, J. Am. Chem. Soc. 135, 8720–8725 (2013)

    Article  Google Scholar 

  27. S.G. Lyapin, A.N. Utyuzh, A.E. Petrova, A.P. Novikov, T.A. Lograsso, S.M. Stishov, J. Phys. Condens. Matter 26, 396001 (2014)

    Article  Google Scholar 

  28. B.J. Tufts, I.L. Abrahams, C.E. Caley, S.R. Lunt, G.M. Miskelly, M.J. Sailor, P.G. Santangelo, N.S. Lewis, A.L. Roe, K.O. Hodgson, J. Am. Chem. Soc. 112, 5123–5136 (1990)

    Article  Google Scholar 

  29. A.G. SchaufuB, H.W. Nesbitt, I. Kartio, K. Laajalehto, G.M. Bancroft, R. Szargan, Surf. Sci. 411, 321–328 (1998)

    Article  Google Scholar 

Download references


This work was supported by the NRF Grant (NRF-2014R1A2A2A01007136) and a Grant (Code No. 2011-0031630) from the Center for Advanced Soft Electronics under the Global Frontier Research Program through the National Research Foundation funded by the Ministry of Science, ICT and Future Planning, Korea and by the framework of Indus-try Convergence Fundamental Technology Development Program (10050509, MOTIE, Korea) of Korea Evaluation Institute of Industrial Technology by the Ministry of Trade, Industry and Energy, Korea.

Competing interests

The authors declare that they have no competing interests.

Author information

Authors and Affiliations


Corresponding author

Correspondence to Hyeon Suk Shin.

Additional information

Seongjoon Ahn and Jieun Yang contributed equally to this work

Additional file


Additional file 1: Figure S1. XRD patterns of CoS /rGO samples synthesized at different temperatures: 200 (black), 240 (red),and 265 C (blue). Figure S2. TEM image of cobalt sulfides without GO: (a) low magnification and (b) high-magnificationimages. The inset in (b) indicates the (111) diffraction pattern of Co S in the white square. Figure S3. EDS elemental mapping of Co and S for CoS /rGO (2.3 mg/mL of GO), EDX spectrum and tableshowing elemental composition. The atomic ratio of S and Co is 2, confirming the stoichiometry of CoS . Figure S4. TEM image of CoS /rGO (1 mg/mL of GO). (a) Bright field TEM image in low magnification (b)High resolution TEM image of CoS particle. (c) High resolution TEM image of a CoS particle which is not covered by rGO. Inset of (b) shows planes of CoS including (311) plane and inset of (c) shows planes of CoS including (100) plane. Figure S5. XRD patterns of the CoS /rGO hybrids with various GO concentrations. Figure S6. (a) Plots for the extraction of the double-layer capacitance (C ) for CoS /rGO electrodes. CV cycles of CoS /rGO samples with 1 mg/mL of GO (b) and 2.3 mg/mL of GO (c) at different scan rates. Figure S7. Polarization curves of CoS /rGO depending on the concentration of GO at (a) higher and (b) lower applied oveportentials show the HER performance. (c) Tafel analysis of the data shown in Figure S5a. (d) Summary of the electrochemical performance for CoS /rGO samples with various GO concentrations. Figure S8. Electrochemical impedance spectroscopy (EIS) for CoS /rGO samples. Figure S9. (a) SEM image of CoS /rGO (2.3 mg/mL of GO) after the cycling test for 14 hours. (b) High resolution TEM image of a CoS particle after the cycling test. Inset of (b) shows planes of CoS including (102) plane. Table S1. Comparison of growth condition for CoS /rGO with other reported cobalt sulfide/rGO materials. Table S2. The weight percentage of rGO in products by elemental analysis. Table S3. Comparison of HER activity measured for our CoS2/rGO with other reported CoS materials as HER catalyst.

Rights and permissions

Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (, which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahn, S., Yang, J., Lim, H. et al. Selective synthesis of pure cobalt disulfide on reduced graphene oxide sheets and its high electrocatalytic activity for hydrogen evolution reaction. Nano Convergence 3, 5 (2016).

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: