# Hyperbolic metamaterials: fundamentals and applications

- Prashant Shekhar
^{1}, - Jonathan Atkinson
^{1}and - Zubin Jacob
^{1}Email author

**1**:14

https://doi.org/10.1186/s40580-014-0014-6

© Shekhar et al.; licensee Springer 2014

**Received: **10 December 2013

**Accepted: **3 March 2014

**Published: **11 June 2014

## Abstract

Metamaterials are nano-engineered media with designed properties beyond those available in nature with applications in all aspects of materials science. In particular, metamaterials have shown promise for next generation optical materials with electromagnetic responses that cannot be obtained from conventional media. We review the fundamental properties of metamaterials with hyperbolic dispersion and present the various applications where such media offer potential for transformative impact. These artificial materials support unique bulk electromagnetic states which can tailor light-matter interaction at the nanoscale. We present a unified view of practical approaches to achieve hyperbolic dispersion using thin film and nanowire structures. We also review current research in the field of hyperbolic metamaterials such as sub-wavelength imaging and broadband photonic density of states engineering. The review introduces the concepts central to the theory of hyperbolic media as well as nanofabrication and characterization details essential to experimentalists. Finally, we outline the challenges in the area and offer a set of directions for future work.

## 1.0 Introduction

Metamaterials research has captured the imagination of optical engineers and materials scientists because of their varied applications including imaging [1–3], cloaking [4, 5], sensing [6], waveguiding [7], and simulating space-time phenomena [8] (Figure 1). The field of metamaterials started with the search for negative dielectric permittivity and magnetic permeability [9] however the range of electromagnetic responses achievable using nanostructured media far surpass the concept of negative index. The invisibility cloak is the best example where an inhomogeneous anisotropic electromagnetic response causes light to bend smoothly around an object rendering it invisible [10]. Another example is that of chiral metamaterials, where the response of a medium to polarized light can be enhanced by orders of magnitude through artificial structures [11, 12].

While all the above media have specific domains of application, hyperbolic metamaterials are a multi-functional platform to realize waveguiding, imaging, sensing, quantum and thermal engineering beyond conventional devices [13–18]. This metamaterial uses the concept of engineering the basic dispersion relation of waves to provide unique electromagnetic modes that can have a broad range of applications [19, 20]. One can consider the hyperbolic metamaterial as a polaritonic crystal where the coupled states of light and matter give rise to a larger bulk density of electromagnetic states [21, 22]. Some of the applications of hyperbolic metamaterials include negative refraction [23, 24], sub-diffraction imaging [3, 25], sub-wavelength modes [7, 26], and spontaneous [27–31] and thermal emission engineering [32–34].

The initial work in artificial structures with hyperbolic behavior started in the microwave regime (indefinite media) with phenomena such as resonance cones [18], negative refraction [35] and canalization of images [15]. In the optical domain, it was proposed that non-magnetic media can show hyperbolic behavior leading to negative index waveguides [14], sub-wavelength imaging [3] and sub-diffraction photonic funnels [7]. This review aims to provide an overview of the properties of hyperbolic media from an experimental perspective focusing on design and characterization [36]. To aid experimentalists, we describe the different experimental realizations of hyperbolic media (thin film and nanowire geometry) and contrast their differences [23, 24]. After initial sections on design and characterization, we also review applications of sub-diffraction imaging and density of states engineering with hyperbolic metamaterials. We give a detailed section for experimentalists to analyze the various figures of merit related to hyperbolic media and spontaneous emission engineering.

*ω*is the frequency of radiation and

*c*is the velocity of light in free space. If we consider an extraordinary wave (TM polarized) in a uniaxial medium, this isofrequency relation changes to

Note the uniaxial medium has a dielectric response given by a tensor$\overleftrightarrow{\mathit{\epsilon}}=\left[{\mathit{\epsilon}}_{\mathit{xx}},{\mathit{\epsilon}}_{\mathit{yy}},{\mathit{\epsilon}}_{\mathit{zz}}\right]$where the in-plane isotropic components are *ε*
_{
xx
} = *ε*
_{
yy
} = *ε*
_{||} and out of plane component is *ε*
_{
zz
} = *ε*
_{⊥}. The spherical isofrequency surface of vacuum distorts to an ellipsoid for the anisotropic case. However, when we have extreme anisotropy such that *ε*
_{||} ⋅ *ε*
_{⊥} < 0, the isofrequency surface opens into an open hyperboloid (Figure 2(b,c)). Such a phenomenon requires the material to behave like a metal in one direction and a dielectric (insulator) in the other. This does not readily occur in nature at optical frequencies but can be achieved using artificial nanostructured electromagnetic media: metamaterials.

The most important property of such media is related to the behavior of waves with large magnitude wavevectors. In vacuum, such large wavevector waves are evanescent and decay exponentially. However, in hyperbolic media the open form of the isofrequency surface allows for propagating waves with infinitely large wavevectors in the idealistic limit [3, 27]. Thus there are no evanescent waves in such a medium. This unique property of propagating high-*k* waves gives rise to a multitude of device applications using hyperbolic media [19, 20].

We introduce a classification for hyperbolic media that helps to identify their properties. Type I HMMs have one component of the dielectric tensor negative (ε_{zz} < 0; ε_{xx}; ε_{yy} > 0) while Type II HMMs have two components negative (ε_{xx}; ε_{yy} < 0; ε_{zz} >0) and are shown in Figure 2(b) and (c), respectively. Note of course, that if all components are negative, we obtain a metal and if all components are positive we will have a dielectric medium. One striking difference between the Type I and Type II hyperbolic metamaterial is that the hyperboloidal surfaces are two sheeted and single sheeted respectively. The Type II metamaterial is highly reflective since it is more metallic than the Type I counterpart [37].

## 2.0 Review

### 2.1 Design and materials

There are two practical approaches to achieve the hyperbolic dispersion which we discuss below. The fact that hyperbolicity requires metallic behavior in one direction and insulating behavior in the other leads to the requirement that both metals and dielectrics must be used as building blocks. Microscopically, the origin of the high-k propagating waves relies on a metallic building block to create the hyperbolic dispersion of the material (section 1.0). The polaritonic properties of the metallic building blocks allow for the necessary light-matter coupling to create the high-k waves. Specifically, it is necessary to have a phonon-polaritonic (optically active phonons) or plasmon-polaritonic (free electron) metal to construct hyperbolic metamaterials. The high-k modes are a result of the near-field coupling of the surface plasmon polaritons (SPPs) at each of the metal-dielectric interfaces in the structure. The high-k modes are the Bloch modes of the metal-dielectric superlattice.

#### a) 1D HMM

A thin film multilayer (super-lattice) consisting of alternating layers of metal and dielectric gives rise to the desired extreme anisotropy [38] (Figure 3(a,b)). The layer thicknesses should be far below the size of the operating wavelength for the homogenization to be valid. A detailed derivation is given in Appendix 1.0. We emphasize right at the outset that the most important figure of merit for the HMM is the plasma frequency of the metal and the loss. These two quantities determine the impedance matching and absorption of the metamaterial for practical applications [39].

A wide choice of plasmonic metals and high index dielectrics can give rise to hyperbolic behavior in different wavelength regimes. At ultraviolet (UV) frequencies, gold and silver along with alumina forms the ideal choice for the metamaterial. Close to the plasma frequency of these metals, which is in the UV, their reflectivity decreases and an alternating metal dielectric super-lattice achieves a Type I HMM with high transmission. To push this design to visible wavelengths however a high index dielectric such as TiO_{2} or SiN is needed [40].

At near-infrared (IR) wavelengths, compensating for the reflective metallic behavior of naturally plasmonic metals like silver and gold is unfeasible and alternate plasmonic materials with tailored lower plasma frequencies are needed. These alternate plasmonic materials are based on transition metal nitrides or transparent conducting oxides and are ideally suited for hyperbolic media [39, 41]. Recently, their unique property of high melting point was also used to pave the way for high temperature thermal hyperbolic metamaterials [42, 43].

At mid-infrared wavelengths, one option for the metallic component in hyperbolic media consists of III-V degenerately doped semiconductors [24, 44]. The upper limit of doping concentration often limits their abilities to work as a metal at near-IR wavelengths, however they are ideally suited to the mid-IR. Another option which is fundamentally different from above mentioned plasmonic metals is silicon carbide, a low loss phonon polaritonic metal [37, 45, 46]. SiC has a narrow reststrahlen band at mid-IR wavelengths which allows it to function as a metallic building block for hyperbolic media. SiC based hyperbolic media were recently predicted to show super-Planckian thermal emission [32, 33]. Multilayer graphene super-lattices can also show a hyperbolic metamaterial response in the THz (far-IR) region of the spectrum [47–51].

#### b) 2D HMM

Another approach to achieving hyperbolic behavior consists of metallic nanowires in a dielectric host [23, 36],[52–54] (Figure 3(c)). The choice of metals are usually silver and gold grown in a nanoporous alumina template. The major advantage of this design is the low losses, broad bandwidth and high transmission. Also, the problem of large reflectivity like the multilayer design does not exist and we can achieve Type I hyperbolic behavior. Note the fill fraction of metal needed in the 2D design to achieve Type I hyperbolic behavior is far below that in the multilayer design leading to a large figure of merit.

### 2.2 Nanofabrication

Here we give a brief overview of the popular techniques used to fabricate hyperbolic metamaterials.

#### a) Thin film

The multilayer design relies extensively on the deposition of ultrathin and smooth thin films of metal and dielectric. Surface roughness is surely an issue for practical applications due to increased material loss and light scattering. However, minor deviations in layer thicknesses do not appreciably change the effective medium response [55–57]. Gold and silver along with alumina or titanium dioxide have been deposited by multiple groups using electron beam evaporation [22, 58]. Typical layer thicknesses can include 22 nm Ag alternated with 40 nm TiO_{2} layers. The alternate plasmonic materials can be made via reactive sputtering or deposited by pulsed laser deposition to maintain the required strict stoichiometry [39]. Silicon carbide can be grown by plasma enhanced chemical vapor deposition (PECVD) [37]. However, it is difficult to observe crystalline behavior crucial for high quality phonon-polariton resonances in multilayer structures. For III-V semiconductors, molecular beam epitaxy (MBE) is the ideal method to grow the alternating layers consisting of highly doped semiconductors behaving as a metal [24]. Extremely uniform and smooth surfaces are possible with MBE.

#### b) Nanowire

The standard procedure consists of either buying off the shelf anodic alumina membrane [36] or anodizing aluminum to grow the required template [6, 59]. Multiple groups have successfully fabricated hyperbolic metamaterials using both of these approaches. This template forms the basic dielectric host medium with a periodic nanoporous structure into which the silver (or gold) nanowires can be electrodeposited. Typical dimensions for recent gold nanowire structures include 20–700 nm long wires with a 10–50 nm rod diameter with 40–70 nm rod separation [6]. Note the porosity controls the fill fraction of the metal and hence the dispersion of hyperbolic behavior. A multi-step controlled electrodeposition is necessary to ensure that the silver filling is consistent across the sample. Furthermore, a significant issue of silver overfilling or discontinuous islands within the pore has to be addressed after fabrication and presents a challenge to successful nanowire HMM fabrication.

### 2.3 Theoretical characterization

We begin this section with a note that characterization of artificial media and effective medium parameter retrieval has been a controversial topic in the field of metamaterials [60]. This is primarily because the unit cells are often not subwavelength and the structures are two dimensional where an effective permittivity cannot be defined in the strict sense [61]. We emphasize that hyperbolic media suffer from neither of these drawbacks. The unit cells in both the 1D and 2D design are always deeply subwavelength (typically 20–70 nm) for propagating states, however, at very large wavevector values, non-local theory must be taken into consideration [62]. The structures are also three dimensional where the effective medium parameters show extreme anisotropy for p-polarized light. We now describe the experimental characteristics that can be used to confirm the presence of hyperbolic behavior in the samples.

#### a) Epsilon-near-zero and epsilon-near-pole responses

An interesting characteristic of multilayer and nanowire structures are the existence of poles and zeros in the effective medium dielectric constants. This results in an ideal method to first characterize the resonant responses and subsequently infer the hyperbolic characteristics. At these specific wavelengths a component of the dielectric tensor of the metamaterial either passes through zero (epsilon-near-zero, ENZ) [63, 64] or has a resonant pole (epsilon-near-pole, ENP) [42].

_{2}with a metallic fill fraction of 35% shows both Type I and Type II hyperbolic behavior. The nanowire effective medium theory (EMT) parameters are shown in Figure 4(b). Type I behavior, which is difficult to achieve with multilayer structures, is observed. It also shows the characteristic ENP and ENZ resonances.

The most important aspect to note about the ENZ and ENP resonances are the directions in which they occur for multilayer and nanowire samples. This fundamentally changes the reflection and transmission spectrum of the two types of hyperbolic media. For the two designs, ENZ occurs parallel to the thin film layers or along the nanowire length. This is intuitively expected since the Drude plasma frequency which determines the ENZ always occurs in the direction of free electron motion. Conversely, the resonant ENP behavior of the two geometries occurs in the direction for which there is no continuous free electron motion. The ENP resonance occurs perpendicular to the thin film layers in the multilayer structure and perpendicular to the wires in the nanowire geometry [42]. The directions of ENZ and ENP behavior for the multilayer and nanowire structures are shown in the schematic insets of Figure 4.

#### b) Propagating wave spectrum

Characterization of the metamaterials is most easily done by analyzing the reflection and transmission spectrum of propagating waves. Note that measuring phase is difficult hence it is preferred to study the angle resolved reflection and transmission spectrum to infer the effective medium parameters. The features of hyperbolic behavior are manifested only in p-polarized light so it is best to study the transverse electric (s-polarized) and p-polarized light separately and contrast the differences [22, 36]. Note, that in the following analysis of the reflection, transmission, and extinction spectra, the structures do differ slightly to highlight key features. Specifics of the structures used for the analysis are highlighted in the figure captions.

*Reflection spectrum*: The Type I metamaterials have only one component of the dielectric tensor negative and are less reflective due to no free electron motion parallel to the interface. They have properties of conventional dielectrics, such as the Brewster angle, which can be used to extract the EMT parameters. Both multilayer and nanowire samples show Type I behavior as can be seen in Figure 5. The Type II metamaterials have two components of the dielectric tensor negative and are highly reflective at all angles (Figure 5(a)). They have properties common to conventional metals such as surface plasmon polaritons. It is easy in multilayer structures to obtain Type II behavior while it is easier in nanowire samples to obtain Type I behavior.

The Brewster angle, the angle for which there is a strong minimum in the reflectance, is seen clearly for the p-polarized Type I reflectance in both the multilayer (Figure 5(a)) and nanowire (Figure 5(b)) structures. Free electron motion parallel to the interface greatly increases the overall reflection for Type II hyperbolic metamaterials and a Brewster angle cannot be defined.

The behavior of the Brewster angle with respect to the wavelength can be used to determine whether the metamaterial exhibits Type I behavior by looking at the propagating spectrum. A discontinuity in the Brewster angle is witnessed at the wavelength where *ε*
_{⊥} ≈ 0 in a Type I hyperbolic metamaterial [24].

*Transmission spectrum*: As discussed, the Type I regime shows high transmission in contrast to other metamaterials where absorption is a major issue. In Figure 6(a) we plot the transmission from a multilayer sample which shows a window of transparency in the Type I region until it becomes very reflective in the Type II regime. The effective medium theory predictions are well matched to the multilayer simulations using an Ag-TiO

_{2}system. Figure 6(b) shows the transmission through the nanowire Type I region. Moving the transmission windows of hyperbolic media to visible wavelengths is a challenge with the multilayer design unless high index dielectrics are used.

*Extinction spectrum:*The nanowire design shows interesting features in the extinction spectrum which arises due to the epsilon-near-zero (ENZ) and epsilon-near-pole (ENP) resonances (Figure 7). The ENZ resonance requires a component perpendicular to the interface and occurs only for p-polarized light. In the nanowire structure, the directions of ENZ and ENP resonances are such that they interact with propagating waves and subsequently lead to large extinction. Specifically, from the displacement boundary condition,

*ε*

_{0}

*E*

_{0⊥}=

*ε*

_{⊥}

*E*

_{1⊥}, and therefore when

*ε*

_{⊥}→ 0, the fields inside the nanowire HMM (

*E*

_{1⊥}) should be very large. Thus large absorption is expected at this epsilon near zero region for this particular nanowire structure. Although this resonance is seen in the multilayer structure, it has free electron motion parallel to the interface and thus greatly reflects the incoming propagating fields. The ENZ and ENP resonances, therefore, do not appear in the multilayer extinction spectrum due to the characteristically higher reflection from increased metallic behavior of such structures.

The ENP resonance occurs for both polarizations. They are often addressed in literature as the L (longitudinal) and T (transverse) resonance corresponding to the direction of plasmonic oscillations in the rod [59].

#### c) Evanescent wave spectrum

The most important characteristic of hyperbolic behavior cannot be discerned by propagating waves alone. This is because multiple applications stem from the high-*k* propagating waves in the medium which are evanescent in vacuum. An optical tunneling experiment is essential to understand the high-*k* waves [65–67]. However a significant issue is that even such an experiment would require high index prisms for in and out-coupling which are not readily available in the visible range. A grating based approach is ideal to study these high-*k* waves [37].

*k*

_{ x }>

*k*

_{0}=

*ω*/

*c*). The propagating waves have

*k*

_{ x }<

*k*

_{ 0 }. Figure 8 shows the effect of increasing the number of layers of silver in the multilayer structure on the transmission spectrum across the visible range. For the thin layer of silver in vacuum we see the bright band corresponding to the characteristic surface plasmon polariton dispersion. When a thin layer of dielectric is added, this bilayer system has an interface plasmon polariton with a shifted resonance frequency as shown in Figure 8(b). Figure 8(c) shows the scenario when there are 8 alternating layers of silver and TiO

_{2}. Interestingly, multiple bands of interface waves are seen. This has to be compared to Figure 8(d) where the effective medium simulation has been shown for a slab of the same total thickness. It thus becomes evident that the high-

*k*waves, which can be interpreted as high-

*k*waveguide modes in the slab geometry, originate from the plasmon polaritons at the interface of silver and TiO

_{2}. The coupling between multiple such polaritons leads to a splitting of modes to higher wavevectors and energies. This is evident in the emergence of new modes as the number of layers are increased. In Figure 8(e)-(h) we show the case of polaritonic high-

*k*waves with a TiO

_{2}thickness of 30 nm and a 10 nm silver thickness for various numbers of alternating layers. It is clear that the increased dielectric ratio (25% fill fraction) of the structure changes the nature of the dispersion of the high-

*k*modes and causes a subsequent shift in the plasma frequency. We see no high-

*k*waves in the elliptical dispersion range for this subwavelength unit cell structure [58]. However, it should be noted that some studies have shown high-

*k*multilayer plasmons in the elliptical dispersion regime [69].

### 2.4 Applications

#### a) Far-field sub-wavelength imaging

One of the major applications of metamaterials has been in the area of subwavelength imaging. Conventional optics is known to be limited by the diffraction limit, i.e., the ability of a conventional lens to focus light or form images is always constrained by the wavelength of the illuminating light.

Note these large wavevector waves carry spatial information about the subwavelength features of the object and decay exponentially. This is due to the spatial bandwidth of vacuum which allows propagating waves with wavevector *k*
_{
x
} *< k*
_{
0
} (Figure 9(b)).

The hyperlens is a device which overcomes this limitation [3, 25, 72, 73]. Evanescent wave energy and information from the near-field can be transferred to the far-field if the layers forming the hyperbolic metamaterial are curved in a cylindrical fashion. The qualitative explanation for this conversion phenomenon is shown in Figure 10(b). Conservation of angular momentum (*m ~ k*
_{
θ
}
*r*) in the cylindrical geometry implies that the tangential part of the momentum for the wave times the radius is a constant. Thus when the high-*k* waves move towards the outer edge of the cylinder, the wavevectors decrease in magnitude. If the radii are carefully chosen, then the wavevectors can be compressed enough to propagate to the far-field. This enables far-field subwavelength resolution using the hyperlens [73, 74].

An important consideration for practical realization and optimization is the additional impedance matching condition imposed on the metal and dielectric building blocks [40, 75]. This condition gives (Re(*ε*
_{
m
} + *ε*
_{
d
}) ≈ 1) for equal layer thicknesses [76]. Note the hyperlens functions in the Type I HMM regime since it requires high transmission. Currently, there are major efforts underway to make the hyperlens into the first metamaterial device with practical applicability in imaging systems.

#### b) Density of states engineering

*k*states dominate and the emitters preferentially couple to these modes [58]. This leads to a decrease in lifetime. Multiple experiments have explored this effect by studying dye molecules and quantum dots on top of the multilayer and nanowire hyperbolic metamaterial. A lifetime shortening has been observed but discerning the radiative and non-radiative effects have proven to be a challenge [19]. Here, we outline the factors underlying the multitude of experiments measuring spontaneous emission lifetime.

- i.
*Absorption enhancement:*One cause of fluorescence enhancement is the increase in the absorption of molecules or quantum dots due to the effect of the environment. The absorption increases due to local field enhancement and is proportional to the local field intensity at the location of the emitter (*A*∝ |*E*|^{2}). It is necessary to keep the absorption constant across samples to reliably compare the photoluminescence enhancement [80]. One approach to achieving this is to function in the saturation regime, where the emitted power is no longer proportional to the input power. In this illumination regime, the fluorophores absorb the maximum possible power leading to a constant steady state excited population for pulsed excitation. Any increase in photoluminescence in this regime can be attributed to enhanced decay rates due to the environment and not absorption enhancement [81, 82].For the case of planar multilayer hyperbolic metamaterials, the absorption enhancement is expected to be a weak effect due to the lack of any localized plasmons which generate field hotspots [83]. Furthermore, the high-

*k*modes cannot be excited by free space illumination and cannot affect the absorption. - ii.
*Photoluminescence enhancement:*In the regime where the output fluorescence signal is independent of the input power (saturation regime), the photoluminescence can be enhanced by increasing the radiative decay rate [84]. This rate depends on the available photonic density of states. Increasing the radiative decay routes for the emitter through the enhancement of the PDOS can be accomplished using microcavities, photonic crystals, plasmonics or metamaterials.The increase in the radiative decay rate is known as the Purcell factor defined as${\mathit{F}}_{\mathit{P}}={\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}/{\mathrm{\Gamma}}_{\mathit{rad}}^{0}$where${\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}$is the enhanced radiative decay rate due to the photonic environment and${\mathrm{\Gamma}}_{\mathit{rad}}^{0}$is the radiative decay rate in vacuum. Notice the environment might also introduce non-radiative channels of decay, and in vacuum the emitter might have intrinsic non-radiative decay channels. Hence, the definition utilizes only radiative decay rates as the correct measure of photoluminescence enhancement. It should be noted that the quantities defined are related to the signal intensity measured at the detector. We can only measure the net decay rate and infer the radiative rate from the PL intensity data with and without the environment [85].

The Purcell factor can also be defined for a mode through the density of states

*F*_{ p }=*ρ*^{ env }(*ω*_{0})/*ρ*^{0}(*ω*_{0}). This theoretical definition does not directly imply a large PL enhancement since the out-coupling factor for the mode into vacuum might be low. For example, a surface plasmon polariton might have a large density of states but unless this surface mode is out-coupled to the detector, the measured PL enhancement will be minimal [58, 86]. It is important to note, therefore, that if one wants to determine the exact PL enhancement, an out-coupling efficiency should be associated with the mode that potentially allows the increased enhancement [87]. It is necessary while comparing theory and experiment to carefully isolate the out-coupling factor and also take into account the overlap of the emitter to the field profile of the mode.In the case of hyperbolic metamaterials, defining a unique modal Purcell factor through the density of states is not possible since the high-

*k*modes form a continuum of available states. Nevertheless, one can define a net enhancement in the density of states as well as PL enhancement [87]. - iii.
*Radiative efficiency:*For applications such as single photon sources, the Purcell factor, photoluminescence enhancement, and collection efficiency form the key figures of merit [87–89]. However, for light emitting diodes the radiative efficiency of the source is essential (i.e. the output photoluminescence for a given input power [84]). A large Purcell factor always implies photoluminescence enhancement (assuming efficient out-coupling of light) since the excited state can relax faster radiatively. The saturation pump power also increases due to the Purcell factor. However, PL enhancement does not necessarily imply radiative efficiency enhancement since it often comes at the cost of larger input powers.To understand this, we define the intrinsic (*η*_{ i }) and apparent quantum yield (*η*_{ a }) of the emitter asand${\mathit{\eta}}_{\mathit{i}}=\frac{{\mathrm{\Gamma}}_{\mathit{rad}}^{0}}{{\mathrm{\Gamma}}_{\mathit{rad}}^{0}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{0}}$(2)${\mathit{\eta}}_{\mathit{a}}=\frac{{\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}}{{\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{\mathit{env}}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{0}}$(3)The intrinsic quantum yield measures the internal radiative efficiency of the emitter and the apparent quantum yield is the final radiative efficiency in the presence of the nanostructures. Note we assume the internal radiative efficiency is constant for interaction distances further than 5 nm.The radiative efficiency enhancement is defined as:$\mathit{F}=\frac{{\mathit{\eta}}_{\mathit{a}}}{{\mathit{\eta}}_{\mathit{i}}}=\frac{{\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}\left({\mathrm{\Gamma}}_{\mathit{rad}}^{0}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{0}\right)}{{\mathrm{\Gamma}}_{\mathit{rad}}^{0}\left({\mathrm{\Gamma}}_{\mathit{rad}}^{\mathit{env}}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{\mathit{env}}+{\mathrm{\Gamma}}_{\mathit{non}-\mathit{rad}}^{0}\right)}$(4)Here, F is the ratio of the apparent to intrinsic quantum yields. The plasmonic or metamaterial environment invariably increases both the radiative and non-radiative rates. Therefore, the radiative efficiency enhancement can only be substantial for emitters with a low intrinsic quantum yield. This is detrimental to applications in LEDs where the primary figure of merit is the radiation efficiency increase.

- iv.
*Decay rate increase/Lifetime shortening*: Time resolved measurements of the spontaneous emission give access to the net decay rate or lifetime of the fluorophore. This rate is always the sum of multiple factors and in particular, the total lifetime (*τ*) near the hyperbolic metamaterial can be written aswhere$\frac{1}{\mathit{\tau}}=\frac{1}{{\mathit{\tau}}_{\mathit{rad}}}+\frac{1}{{\mathit{\tau}}_{\mathit{non}-\mathit{rad}}}$(5)*τ*_{ rad }is the radiative lifetime and*τ*_{ non-rad }is the non-radiative lifetime. Note that the decrease in total lifetime is not indicative of photoluminescence enhancement since the modes into which the light couples are dark (i.e. they don’t out-couple to vacuum). Natural surface roughness of the layers or gratings are needed to out-couple this light to the detector in order to calculate the radiative lifetime experimentally. Figure 11(b) shows the decrease in lifetime of an emitter as it is moved closer to a metamaterial surface [19–28, 90, 91]. - v.
*Quenching:*We now discuss the concept of quenching near metallic structures and hyperbolic metamaterials in particular [92]. In the dipolar approximation, the fluorophores are treated as point emitters with waves of all spatial harmonics emanating from it at the transition frequency. In the near-field of any absorptive structure, the waves with large spatial harmonics are simply absorbed [93, 94]. Since they are the dominant route as compared to vacuum modes for near-field interaction, lifetime decrease occurs primarily due to non-radiative decay. This phenomenon of reduced photoluminescence is known as quenching.

We emphasize that quenching itself is a phenomenon that depends on the local density of states and once competing channels are available at the large wavevectors the non-radiative decay can be overcome. This phenomenon is depicted when comparing Figure 11(c) and (d) where we show the power spectrum of light emitted by fluorophore at a dye distance of 3 nm and 20 nm, respectively. The power spectrum is analogous to the wavevector resolved local density of states. It is seen that when the dye is very close to the surface of the HMM or the silver slab (Figure 11(d)) we see a smooth peak at larger magnitudes of the in plane wavevector (*k*
_{
x
}). This smooth peak is a result of quenching and does not correspond to propagating modes with a well-defined dispersion. One notes that this smooth peak is not evident when the dipole is placed farther away from the structures (Figure 11(c)) where the effects of quenching are reduced. Note that in the effective medium limit, for both the Type I and the Type II structures, we still see the peaks in the LDOS corresponding to the high-*k* modes of the structure when quenching is present. Thus, the nature of the unbounded wavevectors for the hyperbolic metamaterial allow for propagating modes to exist even in the regime where larger quenching effects are taking place. It is interesting to note that silver seems to show a larger decrease to the emitter lifetime when the emitter is placed extremely close to the surface (Figure 11(b)). This can be attributed to a larger smooth quenching peak than the Type I HMM (Figure 11(d)). Type II metamaterials show a larger number of propagating high-*k* modes.

## 3.0 Conclusion and future work

In conclusion, we have reviewed the major applications of hyperbolic media: subwavelength imaging and photonic density of states engineering. To aid experimentalists, we have described the practical approaches of designing and characterizing thin film and nanowire hyperbolic metamaterials. The major future work in this area will be about engineering the coherent, thermal and quantum state of light. These media present a unified platform for building nanoscale light emitters from nanoscale lasers [95, 96] to broadband super-Planckian thermal emitters [32]. Another major direction will be the fluctuational and macroscopic quantum electrodynamics of metamaterials [97]. Hyperbolic media have become an important class of artificial photonic materials for research and is expected to be the first optical metamaterial to find widespread applicability in device applications.

## Appendix 1.0: Effective medium theory for a multilayer system

Here, we will look at deriving the effective medium permittivities for an anisotropic multilayer composite with a uniaxial symmetry. The method follows a generalized Maxwell-Garnett approach to obtain analytical expressions for the effective permittivity in the parallel (*ε*
_{∥} ) and perpendicular (*ε*
_{⊥} ) directions defined below for the multilayer metamaterial.

*ε*

_{ m }and

*ε*

_{ d }respectively. Furthermore, we can define the fill fraction of the total thickness of metal in the system to the total thickness of the metamaterial as follows:

_{m}is the sum of all the thicknesses of metallic layers in the system and d

_{d}is the sum of all the thicknesses of the dielectric layers.

## Effective parallel permittivity

*D*) is proportional to the electric field (

*E*) through the following equation:

*ε*

_{ eff }is the overall effective permittivity of the medium. We know from electrostatics that the tangential component of the electric field must be continuous across an interface as we go from one medium to another. Therefore, we can say

*E*

^{∥}is the electric field of the subwavelength metamaterial. From the continuity of the dielectric displacement in the parallel direction explained above, we can find the overall displacement by averaging the displacement field contributions from the metallic and dielectric components:

## Effective perpendicular permittivity

*E*

^{⊥}is the total electric field in the multilayer system. We can now use our boundary condition from equation (12) and Maxwell’s equation from (2) and substitute them into equation 13. If we cancel out the common electric field terms and solve for

*ε*

_{⊥}, we find the analytic expression for the electric permittivity of the multilayer metamaterial in the perpendicular direction:

## Appendix 2.0: Effective medium theory for a nanowire system

Here we will look at deriving the effective medium permittivities for an anisotropic nanowire composite with a uniaxial symmetry. The method follows a generalized Maxell-Garnett approach to obtain analytical expressions for the effective permittivity in the parallel (*ε*
_{||}) and perpendicular (*ε*
_{⊥}) directions of the nanowire metamaterial.

*ϵ*

_{ m }and

*ϵ*

_{ d }respectively. Furthermore, we can define the fill fraction of nanowires (

*ρ*) in the host material as follows:

The hexagonal unit cell geometry consists of 3 nanowires per unit cell (1 centre wire plus additional partial nanowires at each vertex of the hexagon). *A* is the unit cell area of the hexagon and *a* is the cross sectional area of a single metallic nanowire.

## Effective parallel permittivity

*r).*We note that at a distance

*R*(the radius of the nanowire) we approach the metallic nanowire and dielectric host boundary. Defining our potential inside the nanowire as

*ψ*

_{ 1 }and the potential of the dielectric host as

*ψ*

_{ 2 }, we can make the following assertions about the limits of our potential as well as their behavior at the boundary from known boundary conditions:

*ε*

_{1}and

*ε*

_{2}are the permittivities inside the metallic nanowire and the dielectric host respectively. We can suggest an arbitrary solution for

*ψ*using a trigonometric series expansion for the periodic potential:

*ψ*

_{1}(inside the nanowire) and

*ψ*

_{2}(outside the nanowire) as the following:

We drop the$\frac{1}{{\mathit{r}}^{\mathit{n}}}$term in *ψ*
_{1} (equation 12) and replace the r^{n} term in *ψ*
_{2} (equation 13) with the limit of the potential at *ψ*
_{2} → *∞* = − *E*
_{
o
}
*r* cos *θ*. This ensures non-infinite solutions for the potentials at all values of *r.* Furthermore, we can set the values of the constants K_{1} and K_{2} in equation 12 and equation 13 to 0. This is due to the fact that when we take the derivative of the potential (*ψ*) to eventually find our electric fields, these constants will subsequently disappear.

*ψ*

_{1}) and outside the nanowire (

*ψ*

_{2}). Due to the uniqueness of this trigonometric series expansion we can equate the coefficients of the trigonometric functions for our expression at the boundary.

*A*

_{ n }=

*B*

_{ n }=

*C*

_{ n }=

*D*

_{ n }= 0 because they give impossible boundary conditions. However, we can still use equation 25 and equation 29 to solve for the coefficients

*D*

_{ 1 }and

*B*

_{ 1 }through substitution:

*B*

_{ 1 }which we can substitute into our expression for

*ψ*

_{1}(equation 12) at n = 1:

*E*

_{ 0 }=

*E*

_{ out }

*)*. We can differentiate equation 32 with respect to R to get our expression for the electric field inside the nanowire (

*E*

_{ in }).

*ε*

_{∥}) with two different material mediums is given by:

*E*

_{ in }(equation 33) into equation 34 and make the further substitution that

*ε*

_{1}=

*ε*

_{ m }and

*ε*

_{2}=

*ε*

_{ d }corresponding to the permittivity of the metallic nanorod and dielectric host respectively. Upon making this substitution we arrive at our expression for the parallel component of the permittivity tensor (

*ε*

_{∥}) in terms of the metallic nanorod fill fraction (

*ρ*) and the permittivities of the nanorod (

*ε*

_{ m }) and dielectric host (

*ε*

_{ d })

## Effective perpendicular permittivity

*E*

^{⊥}) along the long axis of the nanowire is continuous at the boundary between the nanowire and the dielectric host.

*E*

^{⊥}is the effective perpendicular field for the subwavelength nanowire metamaterial. We note from Maxwell’s Equations that the displacement field in the perpendicular direction can be defined as

*D*

^{⊥}=

*ε*

_{⊥}

*E*

^{⊥}. We can define our effective perpendicular displacement field by averaging the displacement fields of the metallic nanowires and dielectric host using the metallic fill fraction (

*ρ*).

## Declarations

### Acknowledgements

The authors wish to acknowledge funding from NSERC and the Helmholtz Alberta Initiative. Z. Jacob would like to acknowledge E. E. Narimanov for discussions.

## Authors’ Affiliations

## References

- Pendry JB:
**Negative refraction makes a perfect lens.***Phys. Rev. Lett.*2000,**85**(18):3966–3969. 10.1103/PhysRevLett.85.3966View ArticleGoogle Scholar - Milton GW, Nicorovici NAP, McPhedran RC, Podolskiy VA:
**A proof of superlensing in the quasistatic regime, and limitations of superlenses in this regime due to anomalous localized resonance.***Proc. R. Soc. A*2005,**461**(2064):3999–4034. 10.1098/rspa.2005.1570View ArticleGoogle Scholar - Jacob Z, Alekseyev LV, Narimanov E:
**Optical hyperlens: far-field imaging beyond the diffraction limit.***Opt. Express*2006,**14**(18):8247–8256. 10.1364/OE.14.008247View ArticleGoogle Scholar - Schurig D, Mock JJ, Justice BJ, Cummer SA, Pendry JB, Starr AF, Smith DR:
**Metamaterial electromagnetic cloak at microwave frequencies.***Science*2006,**314**(5801):977–980. 10.1126/science.1133628View ArticleGoogle Scholar - Milton GW, Nicorovici N-AP:
**On the cloaking effects associated with anomalous localized resonance.***Proc. R. Soc. A*2006,**462**(2074):3027–3059. 10.1098/rspa.2006.1715View ArticleGoogle Scholar - Kabashin A, Evans P, Pastkovsky S, Hendren W, Wurtz G, Atkinson R, Pollard R, Podolskiy V, Zayats A:
**Plasmonic nanorod metamaterials for biosensing.***Nat. Mater.*2009,**8**(11):867–871. 10.1038/nmat2546View ArticleGoogle Scholar - Govyadinov AA, Podolskiy VA:
**Metamaterial photonic funnels for subdiffraction light compression and propagation.***Phys. Rev. B*2006,**73**(15):155108. 10.1103/PhysRevB.73.155108View ArticleGoogle Scholar - Smolyaninov II, Hung Y-J:
**Modeling of time with metamaterials.***J. Opt. Soc. Am. B*2011,**28**(7):1591–1595. 10.1364/JOSAB.28.001591View ArticleGoogle Scholar - Cai W, Shalaev V:
*Optical metamaterials: fundamentals and applications Vol. 10*. Springer, Berlin, Germany; (2010).View ArticleGoogle Scholar - Pendry JB, Schurig D, Smith DR:
**Controlling electromagnetic fields.***Science*2006,**312**(5781):1780–1782. 10.1126/science.1125907View ArticleGoogle Scholar - Plum E, Liu XX, Fedotov VA, Chen Y, Tsai DP, Zheludev NI:
**Metamaterials: optical activity without chirality.***Phys. Rev. Lett.*2009,**102**(11):113902. 10.1103/PhysRevLett.102.113902View ArticleGoogle Scholar - Liu N, Liu H, Zhu S, Giessen H:
**Stereometamaterials.***Nat. Photonics*2009,**3**(3):157–162. 10.1038/nphoton.2009.4View ArticleGoogle Scholar - Smith DR, Kolinko P, Schurig D:
**Negative refraction in indefinite media.***J. Opt. Soc. Am. B*2004,**21**(5):1032–1043. 10.1364/JOSAB.21.001032View ArticleGoogle Scholar - Podolskiy VA, Narimanov EE:
**Strongly anisotropic waveguide as a nonmagnetic left-handed system.***Phys. Rev. B*2005,**71**(20):201101. 10.1103/PhysRevB.71.201101View ArticleGoogle Scholar - Belov PA, Simovski CR, Ikonen P:
**Canalization of subwavelength images by electromagnetic crystals.***Phys. Rev. B*2005,**71**(19):193105. 10.1103/PhysRevB.71.193105View ArticleGoogle Scholar - Poddubny A, Iorsh I, Belov P, Kivshar Y:
**Hyperbolic metamaterials.***Nat. Photon*2013,**7**(12):948–957. 10.1038/nphoton.2013.243View ArticleGoogle Scholar - Noginov M, Lapine M, Podolskiy V, Kivshar Y:
**Focus issue: hyperbolic metamaterials.***Opt. Express.*2013,**21**(12):14895–14897. 10.1364/OE.21.014895View ArticleGoogle Scholar - Balmain KG, Luttgen A, Kremer PC:
**Resonance cone formation, reflection, refraction, and focusing in a planar anisotropic metamaterial.***IEEE Antennas Wireless Propag. Lett.*2002,**1:**146–149. 10.1109/LAWP.2002.807565View ArticleGoogle Scholar - Cortes CL, Newman W, Molesky S, Jacob Z:
**Quantum nanophotonics using hyperbolic metamaterials.***J. Opt.*2012,**14**(6):063001. 10.1088/2040-8978/14/6/063001View ArticleGoogle Scholar - Guo Y, Newman W, Cortes CL, Jacob Z:
**Applications of hyperbolic metamaterial substrates.***Adv. OptoElectron.*2012,**2012:**1–9. 10.1155/2012/452502View ArticleGoogle Scholar - Noginov MA, Li H, Barnakov YA, Dryden D, Nataraj G, Zhu G, Bonner CE, Mayy M, Jacob Z, Narimanov EE:
**Controlling spontaneous emission with metamaterials.***Opt. Lett.*2010,**35**(11):1863–1865. 10.1364/OL.35.001863View ArticleGoogle Scholar - Jacob Z, Kim J, Naik G, Boltasseva A, Narimanov E, Shalaev V:
**Engineering photonic density of states using metamaterials.***Appl. Phys. B Lasers Opt.*2010,**100:**215–218. 10.1007/s00340-010-4096-5View ArticleGoogle Scholar - Yao J, Liu Z, Liu Y, Wang Y, Sun C, Bartal G, Stacy AM, Zhang X:
**Optical negative refraction in bulk metamaterials of nanowires.***Science*2008,**321**(5891):930. 10.1126/science.1157566View ArticleGoogle Scholar - Hoffman AJ, Alekseyev L, Howard SS, Franz KJ, Wasserman D, Podolskiy VA, Narimanov EE, Sivco DL, Gmachl C:
**Negative refraction in semiconductor metamaterials.***Nat. Mater.*2007,**6**(12):946–950. 10.1038/nmat2033View ArticleGoogle Scholar - Liu Z, Lee H, Xiong Y, Sun C, Zhang X:
**Far-field optical hyperlens magnifying sub-diffraction-limited objects.***Science*2007,**315**(5819):1686. 10.1126/science.1137368View ArticleGoogle Scholar - Yao J, Yang X, Yin X, Bartal G, Zhang X:
**Three-dimensional nanometer-scale optical cavities of indefinite medium.***Proc. Natl. Acad. Sci.*2011,**108**(28):11327. 10.1073/pnas.1104418108View ArticleGoogle Scholar - Jacob Z, Smolyaninov II, Narimanov EE:
**Broadband purcell effect: radiative decay engineering with metamaterials.***Appl. Phys. Lett.*2012,**100**(18):181105–181105–4. 10.1063/1.4710548View ArticleGoogle Scholar - Iorsh I, Poddubny A, Orlov A, Belov P, Kivshar YS:
**Spontaneous emission enhancement in metal–dielectric metamaterials.***Phys. Lett. A.*2012,**376**(3):185–187. 10.1016/j.physleta.2011.11.001View ArticleGoogle Scholar - Poddubny AN, Belov PA, Kivshar YS:
**Spontaneous radiation of a finite-size dipole emitter in hyperbolic media.***Phys. Rev. A*2011,**84**(2):023807. 10.1103/PhysRevA.84.023807View ArticleGoogle Scholar - Potemkin AS, Poddubny AN, Belov PA, Kivshar YS:
**Green function for hyperbolic media.***Phys. Rev. A*2012,**86**(2):023848. 10.1103/PhysRevA.86.023848View ArticleGoogle Scholar - Poddubny AN, Belov PA, Kivshar YS:
**Purcell effect in wire metamaterials.***Phys. Rev. B*2013,**87**(3):035136. 10.1103/PhysRevB.87.035136View ArticleGoogle Scholar - Guo Y, Cortes CL, Molesky S, Jacob Z:
**Broadband super-Planckian thermal emission from hyperbolic metamaterials.***Appl. Phys. Lett.*2012,**101**(13):131106–131106–5. 10.1063/1.4754616View ArticleGoogle Scholar - Biehs S-A, Tschikin M, Ben-Abdallah P:
**Hyperbolic metamaterials as an analog of a blackbody in the near field.***Phys. Rev. Lett.*2012,**109**(10):104301. 10.1103/PhysRevLett.109.104301View ArticleGoogle Scholar - Nefedov IS, Simovski CR:
**Giant radiation heat transfer through micron gaps.***Phys. Rev. B*2011,**84**(19):195459. 10.1103/PhysRevB.84.195459View ArticleGoogle Scholar - Smith DR, Schurig D:
**Electromagnetic wave propagation in media with indefinite permittivity and permeability tensors.***Phys. Rev. Lett.*2003,**90**(7):077405. 10.1103/PhysRevLett.90.077405View ArticleGoogle Scholar - Noginov M, Barnakov YA, Zhu G, Tumkur T, Li H, Narimanov E:
**Bulk photonic metamaterial with hyperbolic dispersion.***Appl. Phys. Lett.*2009,**94:**151105. 10.1063/1.3115145View ArticleGoogle Scholar - Korobkin D, Neuner B III, Fietz C, Jegenyes N, Ferro G, Shvets G:
**Measurements of the negative refractive index of sub-diffraction waves propagating in an indefinite permittivity medium.***Opt. Exp.*2010,**18**(22):22734–22746. 10.1364/OE.18.022734View ArticleGoogle Scholar - Xiong Y, Liu Z, Sun C, Zhang X:
**Two-dimensional imaging by far-field superlens at visible wavelengths.***Nano Lett.*2007,**7**(11):3360–3365. 10.1021/nl0716449View ArticleGoogle Scholar - Naik GV, Kim J, Boltasseva A:
**Oxides and nitrides as alternative plasmonic materials in the optical range.***Opt. Mater. Express*2011,**1**(6):1090–1099. 10.1364/OME.1.001090View ArticleGoogle Scholar - Lu D, Liu Z:
**Hyperlenses and metalenses for far-field super-resolution imaging.***Nat. Commun.*2012,**3:**1205.Google Scholar - Naik GV, Boltasseva A:
**Semiconductors for plasmonics and metamaterials.***Phys. Status Solidi (RRL)*2010,**4**(10):295–297. 10.1002/pssr.201004269View ArticleGoogle Scholar - Molesky S, Dewalt CJ, Jacob Z:
**High temperature epsilon-near-zero and epsilon-near-pole metamaterial emitters for thermophotovoltaics.***Opt. Express*2013,**21**(S1):A96-A110. 10.1364/OE.21.000A96View ArticleGoogle Scholar - Guo Y, Jacob Z:
**Thermal hyperbolic metamaterials.***Opt. Express*2013,**21**(12):15014–15019. 10.1364/OE.21.015014View ArticleGoogle Scholar - Boltasseva A, Atwater HA:
**Low-loss plasmonic metamaterials.***Science*2011,**331**(6015):290. 10.1126/science.1198258View ArticleGoogle Scholar - Greffet JJ, Carminati R, Joulain K, Mulet JP, Mainguy S, Chen Y:
**Coherent emission of light by thermal sources.***Nature*2002,**416**(6876):61–64. 10.1038/416061aView ArticleGoogle Scholar - Taubner T, Korobkin D, Urzhumov Y, Shvets G, Hillenbrand R:
**Near-field microscopy through a SiC superlens.***Science*2006,**313**(5793):1595–1595. 10.1126/science.1131025View ArticleGoogle Scholar - Iorsh IV, Mukhin IS, Shadrivov IV, Belov PA, Kivshar YS:
**Hyperbolic metamaterials based on multilayer graphene structures.***Phys. Rev. B*2013,**87**(7):075416. 10.1103/PhysRevB.87.075416View ArticleGoogle Scholar - DaSilva AM, Chang Y-C, Norris T, MacDonald AH:
**Enhancement of photonic density of states in finite graphene multilayers.***Phys. Rev. B*2013,**88**(19):195411. 10.1103/PhysRevB.88.195411View ArticleGoogle Scholar - Othman MAK, Guclu C, Capolino F:
**Graphene-based tunable hyperbolic metamaterials and enhanced near-field absorption.***Opt. Express*2013,**21**(6):7614–7632. 10.1364/OE.21.007614View ArticleGoogle Scholar - Othman MAK, Guclu C, Capolino F:
**Graphene–dielectric composite metamaterials: evolution from elliptic to hyperbolic wavevector dispersion and the transverse epsilon-near-zero condition.***J. Nanophoton*2013,**7**(1):073089–073089. 10.1117/1.JNP.7.073089View ArticleGoogle Scholar - Andryieuski A, Lavrinenko AV, Chigrin DN:
**Graphene hyperlens for terahertz radiation.***Phys. Rev. B*2012,**86**(12):121108. 10.1103/PhysRevB.86.121108View ArticleGoogle Scholar - Dickson W, Wurtz G, Evans P, O’Connor D, Atkinson R, Pollard R, Zayats A:
**Dielectric-loaded plasmonic nanoantenna arrays: a metamaterial with tuneable optical properties.***Phys. Rev. B*2007,**76**(11):115411. 10.1103/PhysRevB.76.115411View ArticleGoogle Scholar - Kanungo J, Schilling J:
**Experimental determination of the principal dielectric functions in silver nanowire metamaterials.***Appl. Phys. Lett.*2010,**97:**021903. 10.1063/1.3462311View ArticleGoogle Scholar - Casse B, Lu W, Huang Y, Gultepe E, Menon L, Sridhar S:
**Super-resolution imaging using a three-dimensional metamaterials nanolens.***Appl. Phys. Lett.*2010,**96:**023114. 10.1063/1.3291677View ArticleGoogle Scholar - Chen W, Thoreson MD, Ishii S, Kildishev AV, Shalaev VM:
**Ultra-thin ultra-smooth and low-loss silver films on a germanium wetting layer.***Opt. Express*2010,**18**(5):5124–5134. 10.1364/OE.18.005124View ArticleGoogle Scholar - Nagpal P, Lindquist NC, Oh S-H, Norris DJ:
**Ultrasmooth patterned metals for plasmonics and metamaterials.***Science*2009,**325**(5940):594–597. 10.1126/science.1174655View ArticleGoogle Scholar - Liu H, Wang B, Leong ES, Yang P, Zong Y, Si G, Teng J, Maier SA:
**Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer.***ACS Nano*2010,**4**(6):3139–3146. 10.1021/nn100466pView ArticleGoogle Scholar - Krishnamoorthy HNS, Jacob Z, Narimanov E, Kretzschmar I, Menon VM:
**Topological transitions in metamaterials.***Science*2012,**336**(6078):205–209. 10.1126/science.1219171View ArticleGoogle Scholar - Pollard R, Murphy A, Hendren W, Evans P, Atkinson R, Wurtz G, Zayats A, Podolskiy VA:
**Optical nonlocalities and additional waves in epsilon-near-zero metamaterials.***Phys. Rev. Lett.*2009,**102**(12):127405. 10.1103/PhysRevLett.102.127405View ArticleGoogle Scholar - Smith DR, Vier DC, Koschny T, Soukoulis CM:
**Electromagnetic parameter retrieval from inhomogeneous metamaterials.***Phys. Rev. E.*2005,**71**(3):036617. 10.1103/PhysRevE.71.036617View ArticleGoogle Scholar - Stockman MI:
**Spaser action, loss compensation, and stability in plasmonic systems with gain.***Phys. Rev. Lett.*2011,**106**(15):156802. 10.1103/PhysRevLett.106.156802View ArticleGoogle Scholar - Chebykin AV, Orlov AA, Vozianova AV, Maslovski SI, Kivshar YS, Belov PA:
**Nonlocal effective medium model for multilayered metal-dielectric metamaterials.***Phys. Rev. B*2011,**84**(11):115438. 10.1103/PhysRevB.84.115438View ArticleGoogle Scholar - Alù A, Silveirinha MG, Salandrino A, Engheta N:
**Epsilon-near-zero metamaterials and electromagnetic sources: tailoring the radiation phase pattern.***Phys. Rev. B*2007,**75**(15):155410. 10.1103/PhysRevB.75.155410View ArticleGoogle Scholar - Silveirinha M, Engheta N:
**Tunneling of electromagnetic energy through subwavelength channels and bends using ε-near-zero materials.***Phys. Rev. Lett.*2006,**97**(15):157403. 10.1103/PhysRevLett.97.157403View ArticleGoogle Scholar - Elser J, Podolskiy VA, Salakhutdinov I, Avrutsky I:
**Nonlocal effects in effective-medium response of nanolayered metamaterials.***Appl. Phys. Lett.*2007,**90**(19):191109–191109. 10.1063/1.2737935View ArticleGoogle Scholar - Kidwai O, Zhukovsky SV, Sipe JE:
**Effective-medium approach to planar multilayer hyperbolic metamaterials: Strengths and limitations.***Phys. Rev. A*2012,**85**(5):053842. 10.1103/PhysRevA.85.053842View ArticleGoogle Scholar - Schilling J:
**Uniaxial metallo-dielectric metamaterials with scalar positive permeability.***Phys. Rev. E.*2006,**74**(4):046618. 10.1103/PhysRevE.74.046618View ArticleGoogle Scholar - Zhukovsky SV, Kidwai O, Sipe JE:
**Physical nature of volume plasmon polaritons in hyperbolic metamaterials.***Opt. Express*2013,**21**(12):14982–14987. 10.1364/OE.21.014982View ArticleGoogle Scholar - Orlov AA, Voroshilov PM, Belov PA, Kivshar YS:
**Engineered optical nonlocality in nanostructured metamaterials.***Phys. Rev. B*2011,**84**(4):045424. 10.1103/PhysRevB.84.045424View ArticleGoogle Scholar - Felsen LB, Marcuvitz N:
*Radiation and scattering of waves. Piscataway*. NJ:, IEEE press; (1994).View ArticleGoogle Scholar - Ramakrishna SA, Pendry JB, Wiltshire MCK, Stewart WJ:
**Imaging the near field.***J. Mod. Opt.*2003,**50**(9):1419–1430. 10.1080/09500340308235215View ArticleGoogle Scholar - Salandrino A, Engheta N:
**Far-field subdiffraction optical microscopy using metamaterial crystals: theory and simulations.***Phys. Rev. B*2006,**74**(7):75103. 10.1103/PhysRevB.74.075103View ArticleGoogle Scholar - Smolyaninov II, Hung YJ, Davis CC:
**Magnifying superlens in the visible frequency range.***Science*2007,**315**(5819):1699. 10.1126/science.1138746View ArticleGoogle Scholar - Jacob Z, Narimanov EE:
**Optical hyperspace for plasmons: Dyakonov states in metamaterials.***Appl. Phys. Lett.*2008,**93:**221109. 10.1063/1.3037208View ArticleGoogle Scholar - Kildishev AV, Chettiar UK, Jacob Z, Shalaev VM, Narimanov EE:
**Materializing a binary hyperlens design.***Appl. Phys. Lett.*2009,**94**(7):071102–071102. 10.1063/1.3081403View ArticleGoogle Scholar - Kildishev AV, Narimanov EE:
**Impedance-matched hyperlens.***Opt. Lett.*2007,**32**(23):3432–3434. 10.1364/OL.32.003432View ArticleGoogle Scholar - Narimanov E, Smolyaninov I:
*Beyond Stefan-Boltzmann Law: Thermal Hyper-Conductivity*. (2012).Google Scholar - Narimanov E, Noginov MA, Li H, Barnakov Y:
*Darker than Black: Radiation-absorbing Metamaterial*. (2010).Google Scholar - Lounis B, Orrit M:
**Single-photon sources.***Rep. Prog. Phys.*2005,**68:**1129. 10.1088/0034-4885/68/5/R04View ArticleGoogle Scholar - Kim J, Drachev VP, Jacob Z, Naik GV, Boltasseva A, Narimanov EE, Shalaev VM:
**Improving the radiative decay rate for dye molecules with hyperbolic metamaterials.***Opt. Express*2012,**20:**8100–8116. 10.1364/OE.20.008100View ArticleGoogle Scholar - Khurgin JB, Sun G, Soref RA:
**Practical limits of absorption enhancement near metal nanoparticles.***Appl. Phys. Lett.*2009,**94**(7):071103–071103. 10.1063/1.3081631View ArticleGoogle Scholar - Gérard J-M, Gayral B:
**Strong Purcell effect for InAs quantum boxes in three-dimensional solid-state microcavities.***J. Lightwave Technol.*1999,**17**(11):2089–2095. 10.1109/50.802999View ArticleGoogle Scholar - Tumkur TU, Gu L, Kitur JK, Narimanov EE, Noginov MA:
**Control of absorption with hyperbolic metamaterials.***Appl. Phys. Lett.*2012,**100**(16):161103–161103. 10.1063/1.4703931View ArticleGoogle Scholar - Sun G, Khurgin JB, Soref RA:
**Practical enhancement of photoluminescence by metal nanoparticles.***Appl. Phys. Lett.*2009,**94**(10):101103–101103. 10.1063/1.3097025View ArticleGoogle Scholar - Tanaka K, Plum E, Ou JY, Uchino T, Zheludev NI:
**Multifold enhancement of quantum dot luminescence in plasmonic metamaterials.***Phys. Rev. Lett.*2010,**105**(22):227403. 10.1103/PhysRevLett.105.227403View ArticleGoogle Scholar - Sun G, Khurgin JB, Soref RA:
**Practicable enhancement of spontaneous emission using surface plasmons.***Appl. Phys. Lett.*2007,**90:**111107. 10.1063/1.2539745View ArticleGoogle Scholar - Newman WD, Cortes CL, Jacob Z:
**Enhanced and directional single-photon emission in hyperbolic metamaterials.***JOSA B*2013,**30**(4):766–775. 10.1364/JOSAB.30.000766View ArticleGoogle Scholar - Babinec TM, Hausmann B, Khan M, Zhang Y, Maze JR, Hemmer PR, Loncar M:
**A diamond nanowire single-photon source.***Nat. Nanotechnol.*2010,**5**(3):195. 10.1038/nnano.2010.6View ArticleGoogle Scholar - Esteban R, Teperik TV, Greffet JJ:
**Optical patch antennas for single photon emission using surface plasmon resonances.***Phys. Rev. Lett.*2010,**104**(2):26802. 10.1103/PhysRevLett.104.026802View ArticleGoogle Scholar - Kidwai O, Zhukovsky SV, Sipe JE:
**Dipole radiation near hyperbolic metamaterials: applicability of effective-medium approximation.***Opt. Lett.*2011,**36**(13):2530–2532. 10.1364/OL.36.002530View ArticleGoogle Scholar - Yan W, Wubs M, Mortensen NA:
**Hyperbolic metamaterials: Nonlocal response regularizes broadband supersingularity.***Phys. Rev. B*2012,**86**(20):205429. 10.1103/PhysRevB.86.205429View ArticleGoogle Scholar - Jun YC, Pala R, Brongersma ML:
**Strong modification of quantum dot spontaneous emission via gap plasmon coupling in metal nanoslits†.***J. Phys. Chem. C*2009,**114**(16):7269–7273. 10.1021/jp9083376View ArticleGoogle Scholar - Ford G, Weber W:
**Electromagnetic interactions of molecules with metal surfaces.***Phys. Rep.*1984,**113**(4):195–287. 10.1016/0370-1573(84)90098-XView ArticleGoogle Scholar - Chance RR, Prock A, Silbey R:
**Molecular fluorescence and energy transfer near interfaces.***Adv. Chem. Phys.*1978,**37**(1):65.Google Scholar - Bergman DJ, Stockman MI:
**Surface plasmon amplification by stimulated emission of radiation: quantum generation of coherent surface plasmons in nanosystems.***Phys. Rev. Lett.*2003,**90**(2):27402. 10.1103/PhysRevLett.90.027402View ArticleGoogle Scholar - Cortes CL, Jacob Z:
**Photonic analog of a van Hove singularity in metamaterials.***Phys. Rev. B*2013,**88**(4):045407. 10.1103/PhysRevB.88.045407View ArticleGoogle Scholar - Scheel S, Buhmann S:
**Macroscopic quantum electrodynamics - Concepts and applications.***Acta. Physica. Slovaca*2008,**58**(5):675–809. Reviews and TutorialsGoogle Scholar

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